Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application

Bing Han Li; Sue Lein Wang; Souvik Pal; Pamela Berilyn So; Guan Ying Chen; Wei Jie Huang; Yu Ling Hsu; Szu Yu Kuo; Jui Ming Yeh; Chia Her Lin

doi:10.1016/j.micromeso.2021.111319

Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application

Bing Han Li
, Sue Lein Wang^*
, Souvik Pal
, Pamela Berilyn So
, Guan Ying Chen
, Wei Jie Huang
, Yu Ling Hsu
, Szu Yu Kuo
, Jui Ming Yeh^*
, Chia Her Lin^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

25 引文斯高帕斯（Scopus）

摘要

Four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. In this work, it was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C₁₈-5% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm². Furthermore, the doping of hydrophobic MOFs into PANI can also increases the composite's surface hydrophobicity and improve its gas barrier performance.

原文	英語
文章編號	111319
期刊	Microporous and Mesoporous Materials
卷	325
DOIs	https://doi.org/10.1016/j.micromeso.2021.111319
出版狀態	已發佈 - 2021 10月

ASJC Scopus subject areas

一般化學
一般材料科學
凝聚態物理學
材料力學

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10.1016/j.micromeso.2021.111319

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引用此

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title = "Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application",

abstract = "Four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. In this work, it was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C18-5\% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm2. Furthermore, the doping of hydrophobic MOFs into PANI can also increases the composite's surface hydrophobicity and improve its gas barrier performance.",

keywords = "Anticorrosion, Hydrophobic, Metal-organic frameworks, Polyaniline, Post-synthetic modification",

author = "Li, \{Bing Han\} and Wang, \{Sue Lein\} and Souvik Pal and So, \{Pamela Berilyn\} and Chen, \{Guan Ying\} and Huang, \{Wei Jie\} and Hsu, \{Yu Ling\} and Kuo, \{Szu Yu\} and Yeh, \{Jui Ming\} and Lin, \{Chia Her\}",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Inc.",

year = "2021",

month = oct,

doi = "10.1016/j.micromeso.2021.111319",

language = "English",

volume = "325",

journal = "Microporous and Mesoporous Materials",

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TY - JOUR

T1 - Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application

AU - Li, Bing Han

AU - Wang, Sue Lein

AU - Pal, Souvik

AU - So, Pamela Berilyn

AU - Chen, Guan Ying

AU - Huang, Wei Jie

AU - Hsu, Yu Ling

AU - Kuo, Szu Yu

AU - Yeh, Jui Ming

AU - Lin, Chia Her

PY - 2021/10

Y1 - 2021/10

N2 - Four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. In this work, it was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C18-5% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm2. Furthermore, the doping of hydrophobic MOFs into PANI can also increases the composite's surface hydrophobicity and improve its gas barrier performance.

AB - Four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. In this work, it was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C18-5% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm2. Furthermore, the doping of hydrophobic MOFs into PANI can also increases the composite's surface hydrophobicity and improve its gas barrier performance.

KW - Anticorrosion

KW - Hydrophobic

KW - Metal-organic frameworks

KW - Polyaniline

KW - Post-synthetic modification

UR - https://www.scopus.com/pages/publications/85112350340

UR - https://www.scopus.com/pages/publications/85112350340#tab=citedBy

U2 - 10.1016/j.micromeso.2021.111319

DO - 10.1016/j.micromeso.2021.111319

M3 - Article

AN - SCOPUS:85112350340

SN - 1387-1811

VL - 325

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

M1 - 111319

ER -

Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application

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ASJC Scopus subject areas

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