@article{90d8c9820c23425b84f458c3feb610fd,
title = "Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application",
abstract = "Four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. In this work, it was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C18-5% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm2. Furthermore, the doping of hydrophobic MOFs into PANI can also increases the composite's surface hydrophobicity and improve its gas barrier performance.",
keywords = "Anticorrosion, Hydrophobic, Metal-organic frameworks, Polyaniline, Post-synthetic modification",
author = "Li, {Bing Han} and Wang, {Sue Lein} and Souvik Pal and So, {Pamela Berilyn} and Chen, {Guan Ying} and Huang, {Wei Jie} and Hsu, {Yu Ling} and Kuo, {Szu Yu} and Yeh, {Jui Ming} and Lin, {Chia Her}",
note = "Funding Information: This research was supported by the Ministry of Science and Technology ( MOST 107-2113-M-003-017-MY2 and MOST 107-2628-M-003-005-MY3 ), Frontier Research Center on Fundamental and Applied Sciences of Matters ( MOST 107-3017-F-007-002 ) and the National Synchrotron Radiation Research Center of Taiwan . Publisher Copyright: {\textcopyright} 2021 Elsevier Inc.",
year = "2021",
month = oct,
doi = "10.1016/j.micromeso.2021.111319",
language = "English",
volume = "325",
journal = "Microporous and Mesoporous Materials",
issn = "1387-1811",
publisher = "Elsevier",
}