Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Chien Nan Lin; Wei Ting Jhu; Minghuey Shieh

doi:10.1039/c3cc48303g

Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Chien Nan Lin, Wei Ting Jhu, Minghuey Shieh^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

8 引文斯高帕斯（Scopus）

摘要

A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe₃Cu₂-based cluster [((μ₃-S)Fe₃(CO)₉)Cu₂(dppe)] (2) and its 1D polymer [((μ₄-S)Fe₃(CO)₉)Cu₂(dppe)(MeCN)₂]_n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

原文	英語
頁（從 - 到）	1134-1136
頁數	3
期刊	Chemical Communications
卷	50
發行號	9
DOIs	https://doi.org/10.1039/c3cc48303g
出版狀態	已發佈 - 2014 12月 24

ASJC Scopus subject areas

催化
電子、光磁材料
陶瓷和複合材料
化學 (全部)
表面、塗料和薄膜
金屬和合金
材料化學

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10.1039/c3cc48303g

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title = "Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters",

abstract = "A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.",

author = "Lin, {Chien Nan} and Jhu, {Wei Ting} and Minghuey Shieh",

year = "2014",

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doi = "10.1039/c3cc48303g",

language = "English",

volume = "50",

pages = "1134--1136",

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T1 - Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

AU - Lin, Chien Nan

AU - Jhu, Wei Ting

AU - Shieh, Minghuey

PY - 2014/12/24

Y1 - 2014/12/24

N2 - A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

AB - A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

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DO - 10.1039/c3cc48303g

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 9

ER -

Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

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