Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Chien Nan Lin; Wei Ting Jhu; Minghuey Shieh

doi:10.1039/c3cc48303g

Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Chien Nan Lin, Wei Ting Jhu, Minghuey Shieh^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

11 引文斯高帕斯（Scopus）

摘要

A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe₃Cu₂-based cluster [((μ₃-S)Fe₃(CO)₉)Cu₂(dppe)] (2) and its 1D polymer [((μ₄-S)Fe₃(CO)₉)Cu₂(dppe)(MeCN)₂]_n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

原文	英語
頁（從 - 到）	1134-1136
頁數	3
期刊	Chemical Communications
卷	50
發行號	9
DOIs	https://doi.org/10.1039/c3cc48303g
出版狀態	已發佈 - 2014 12月 24

ASJC Scopus subject areas

催化
電子、光磁材料
陶瓷和複合材料
一般化學
表面、塗料和薄膜
金屬和合金
材料化學

存取文件

10.1039/c3cc48303g

其它文件與鏈接

CCDC 930775: Experimental Crystal Structure Determination
Lin, C. (Creator), Jhu, W. (Creator) & Shieh, M. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc107k0t, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc107k0t&sid=DataCite
資料集: Dataset
CCDC 930776: Experimental Crystal Structure Determination
Lin, C. (Creator), Jhu, W. (Creator) & Shieh, M. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc107k1v, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc107k1v&sid=DataCite
資料集: Dataset
CCDC 930774: Experimental Crystal Structure Determination
Lin, C. (Creator), Jhu, W. (Creator) & Shieh, M. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc107jzr, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc107jzr&sid=DataCite
資料集: Dataset

引用此

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title = "Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters",

abstract = "A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.",

author = "Lin, {Chien Nan} and Jhu, {Wei Ting} and Minghuey Shieh",

year = "2014",

month = dec,

day = "24",

doi = "10.1039/c3cc48303g",

language = "English",

volume = "50",

pages = "1134--1136",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

AU - Lin, Chien Nan

AU - Jhu, Wei Ting

AU - Shieh, Minghuey

PY - 2014/12/24

Y1 - 2014/12/24

N2 - A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

AB - A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

UR - http://www.scopus.com/inward/record.url?scp=84891278756&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84891278756&partnerID=8YFLogxK

U2 - 10.1039/c3cc48303g

DO - 10.1039/c3cc48303g

M3 - Article

AN - SCOPUS:84891278756

SN - 1359-7345

VL - 50

SP - 1134

EP - 1136

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 930775: Experimental Crystal Structure Determination

CCDC 930776: Experimental Crystal Structure Determination

CCDC 930774: Experimental Crystal Structure Determination

引用此