Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Chien Nan Lin, Wei Ting Jhu, Minghuey Shieh

研究成果: 雜誌貢獻文章同行評審

7 引文 斯高帕斯(Scopus)

摘要

A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

原文英語
頁(從 - 到)1134-1136
頁數3
期刊Chemical Communications
50
發行號9
DOIs
出版狀態已發佈 - 2014 十二月 24

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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