Unusual photoluminescence behavior of C70

S. M. Argentine, A. H. Francis*, Chia Chun Chen, C. M. Lieber, J. S. Siegel

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

24 引文 斯高帕斯(Scopus)

摘要

Well-resolved photoluminescence (PL) spectra of C70 and 13C70 in a glassy methylcyclohexane matrix have been obtained over the range 10 000-16 000 cm-1 at temperatures between 4 and 77 K. The PL spectrum consists of a short-lived, red fluorescence system extending from 14000 to 15500 cm-1 and a longer-lived, IR phosphorescence system extending from 10 000 to 12 500 cm-1. The PL spectrum is unusual in several aspects: the line widths are nearly 10-fold narrower than those of catacondensed hydrocarbons under similar conditions, and the temperature dependence suggests the presence of multiple emitting states (of the same spin multiplicity) or several emitting species in the highly dilute glassy matrix. To better understand the photophysical behavior of C70, we have attempted to correlate vibrational frequencies in the IR and Raman spectra of C70 and 13C70 with the vibronic intervals observed in the PL spectra. The study of 13C70 enabled a more detailed analysis of the vibronic structure of the fluorescence and phosphorescence spectra.

原文英語
頁(從 - 到)7350-7354
頁數5
期刊Journal of physical chemistry
98
發行號30
DOIs
出版狀態已發佈 - 1994

ASJC Scopus subject areas

  • 工程 (全部)
  • 物理與理論化學

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