Ultra-thin 2D transition metal monochalcogenide crystals by planarized reactions

Hao Ting Chin, Mario Hofmann, Su Yu Huang, Song Fu Yao, Jian Jhang Lee, Chia Chun Chen, Chu Chi Ting, Ya Ping Hsieh*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

摘要

We here present a planarized solid-state chemical reaction that can produce transition metal monochalcogenide (TMMC) 2D crystals with large lateral extent and finely controllable thickness down to individual layers. The enhanced lateral diffusion of a gaseous reactant at the interface between a solid precursor and graphene was found to provide a universal route towards layered TMMCs of different compositions. A unique layer-by-layer growth mechanism yields atomically abrupt crystal interfaces and kinetically controllable thickness down to a single TMMC layer. Our approach stabilizes 2D crystals with commonly unattainable thermodynamic phases, such as β-Cu2S and γ-CuSe, and spectroscopic characterization reveals ultra-large phase transition depression and interesting electronic properties. The presented ability to produce large-scale 2D crystals with high environmental stability was applied to highly sensitive and fast optoelectronic sensors. Our approach extends the morphological, compositional, and thermodynamic complexity of 2D materials.

原文英語
文章編號28
期刊npj 2D Materials and Applications
5
發行號1
DOIs
出版狀態已發佈 - 2021 十二月

ASJC Scopus subject areas

  • 材料科學(全部)
  • 機械工業
  • 材料力學
  • 凝聚態物理學
  • 化學 (全部)

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