Triphenylphosphine-mediated reduction of electron-deficient propargyl ethers to the allylic ethers

Ming Shan Tsai, U. Narasimha Rao, Jeng Rong Wang, Chung Hao Liang, Ming Chang P. Yeh

研究成果: 雜誌貢獻文章

3 引文 斯高帕斯(Scopus)

摘要

Semihydrogenation of α,β-unsaturated ynoates and -ynones bearing a γ-alkoxy group can be performed using triphenylphosphine and water. α,β-Unsaturated ynoates were reduced to a mixture of cis and trans α,β-unsaturated enoates, whereas, ynones were reduced to trans α,β-unsaturated enones as the only products.

原文英語
頁(從 - 到)869-876
頁數8
期刊Journal of the Chinese Chemical Society
48
發行號5
DOIs
出版狀態已發佈 - 2001 一月 1

ASJC Scopus subject areas

  • Chemistry(all)

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