Triphenylphosphine-mediated reduction of electron-deficient propargyl ethers to the allylic ethers

Ming Shan Tsai; U. Narasimha Rao; Jeng Rong Wang; Chung Hao Liang; Ming Chang P. Yeh

doi:10.1002/jccs.200100126

Triphenylphosphine-mediated reduction of electron-deficient propargyl ethers to the allylic ethers

Ming Shan Tsai, U. Narasimha Rao, Jeng Rong Wang, Chung Hao Liang, Ming Chang P. Yeh

化學系

研究成果: 雜誌貢獻 › 文章

3 引文斯高帕斯（Scopus）

摘要

Semihydrogenation of α,β-unsaturated ynoates and -ynones bearing a γ-alkoxy group can be performed using triphenylphosphine and water. α,β-Unsaturated ynoates were reduced to a mixture of cis and trans α,β-unsaturated enoates, whereas, ynones were reduced to trans α,β-unsaturated enones as the only products.

原文	英語
頁（從 - 到）	869-876
頁數	8
期刊	Journal of the Chinese Chemical Society
卷	48
發行號	5
DOIs	https://doi.org/10.1002/jccs.200100126
出版狀態	已發佈 - 2001 一月 1

ASJC Scopus subject areas

Chemistry(all)

存取文件

10.1002/jccs.200100126

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引用此

Tsai, M. S., Rao, U. N., Wang, J. R., Liang, C. H., & Yeh, M. C. P. (2001). Triphenylphosphine-mediated reduction of electron-deficient propargyl ethers to the allylic ethers. Journal of the Chinese Chemical Society, 48(5), 869-876. https://doi.org/10.1002/jccs.200100126

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abstract = "Semihydrogenation of α,β-unsaturated ynoates and -ynones bearing a γ-alkoxy group can be performed using triphenylphosphine and water. α,β-Unsaturated ynoates were reduced to a mixture of cis and trans α,β-unsaturated enoates, whereas, ynones were reduced to trans α,β-unsaturated enones as the only products.",

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AU - Rao, U. Narasimha

AU - Wang, Jeng Rong

AU - Liang, Chung Hao

AU - Yeh, Ming Chang P.

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KW - Propargyl ether

KW - Semihydrogenation

KW - Triphenylphosphine

KW - α,β-Unsaturated enoate

KW - α,β-Unsaturated enone

KW - α,β-Unsaturated ynoate

KW - α,β-Unsaturated ynone

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