Toward carboxylate group functionalized A4, A2B 2, A3B oxaporphyrins and zinc complex of oxaporphyrins

Ram Ambre, Chien Yi Yu, Sandeep B. Mane, Ching Fa Yao, Chen Hsiung Hung*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

16 引文 斯高帕斯(Scopus)

摘要

Series of new oxaporphyrins were isolated from the reaction of furan-1,4-diol, pyrrole, and an aldehyde under Lindsey's conditions, which gives easy access to ester group functionalized oxaporphyrins. The ester substituents can be readily hydrolyzed to terminal carboxylic acid in the presence of KOH. The Zn(II) oxaporphyrins have been synthesized from the reaction of free base with ZnCl2 and fully characterized by variable temperature NMR, 2D NMR, and single crystal X-ray diffraction studies.

原文英語
頁(從 - 到)4680-4688
頁數9
期刊Tetrahedron
67
發行號25
DOIs
出版狀態已發佈 - 2011 6月 24

ASJC Scopus subject areas

  • 生物化學
  • 藥物發現
  • 有機化學

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