Toward carboxylate group functionalized A4, A2B 2, A3B oxaporphyrins and zinc complex of oxaporphyrins

Ram Ambre; Chien Yi Yu; Sandeep B. Mane; Ching Fa Yao; Chen Hsiung Hung

doi:10.1016/j.tet.2011.04.034

Toward carboxylate group functionalized A₄, A₂B ₂, A₃B oxaporphyrins and zinc complex of oxaporphyrins

Ram Ambre, Chien Yi Yu, Sandeep B. Mane, Ching Fa Yao, Chen Hsiung Hung^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

16 引文斯高帕斯（Scopus）

摘要

Series of new oxaporphyrins were isolated from the reaction of furan-1,4-diol, pyrrole, and an aldehyde under Lindsey's conditions, which gives easy access to ester group functionalized oxaporphyrins. The ester substituents can be readily hydrolyzed to terminal carboxylic acid in the presence of KOH. The Zn(II) oxaporphyrins have been synthesized from the reaction of free base with ZnCl₂ and fully characterized by variable temperature NMR, 2D NMR, and single crystal X-ray diffraction studies.

原文	英語
頁（從 - 到）	4680-4688
頁數	9
期刊	Tetrahedron
卷	67
發行號	25
DOIs	https://doi.org/10.1016/j.tet.2011.04.034
出版狀態	已發佈 - 2011 6月 24

ASJC Scopus subject areas

生物化學
藥物發現
有機化學

存取文件

10.1016/j.tet.2011.04.034

其它文件與鏈接

CCDC 809694: Experimental Crystal Structure Determination
Ambre, R. (Creator), Yu, C.-Y. (Creator), Mane, S. B. (Creator), Yao, C.-F. (Creator) & Hung, C.-H. (Creator), Unknown Publisher, 2011
DOI: 10.5517/ccw5k5r, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw5k5r&sid=DataCite
資料集: Dataset

引用此

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title = "Toward carboxylate group functionalized A4, A2B 2, A3B oxaporphyrins and zinc complex of oxaporphyrins",

abstract = "Series of new oxaporphyrins were isolated from the reaction of furan-1,4-diol, pyrrole, and an aldehyde under Lindsey's conditions, which gives easy access to ester group functionalized oxaporphyrins. The ester substituents can be readily hydrolyzed to terminal carboxylic acid in the presence of KOH. The Zn(II) oxaporphyrins have been synthesized from the reaction of free base with ZnCl2 and fully characterized by variable temperature NMR, 2D NMR, and single crystal X-ray diffraction studies.",

keywords = "Core-Modified Porphyrin, Oxaporphyrin, Porphyrin Synthesis, X-ray structure, Zinc Porphyrin",

author = "Ram Ambre and Yu, {Chien Yi} and Mane, {Sandeep B.} and Yao, {Ching Fa} and Hung, {Chen Hsiung}",

year = "2011",

month = jun,

day = "24",

doi = "10.1016/j.tet.2011.04.034",

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T1 - Toward carboxylate group functionalized A4, A2B 2, A3B oxaporphyrins and zinc complex of oxaporphyrins

AU - Ambre, Ram

AU - Yu, Chien Yi

AU - Mane, Sandeep B.

AU - Yao, Ching Fa

AU - Hung, Chen Hsiung

PY - 2011/6/24

Y1 - 2011/6/24

N2 - Series of new oxaporphyrins were isolated from the reaction of furan-1,4-diol, pyrrole, and an aldehyde under Lindsey's conditions, which gives easy access to ester group functionalized oxaporphyrins. The ester substituents can be readily hydrolyzed to terminal carboxylic acid in the presence of KOH. The Zn(II) oxaporphyrins have been synthesized from the reaction of free base with ZnCl2 and fully characterized by variable temperature NMR, 2D NMR, and single crystal X-ray diffraction studies.

AB - Series of new oxaporphyrins were isolated from the reaction of furan-1,4-diol, pyrrole, and an aldehyde under Lindsey's conditions, which gives easy access to ester group functionalized oxaporphyrins. The ester substituents can be readily hydrolyzed to terminal carboxylic acid in the presence of KOH. The Zn(II) oxaporphyrins have been synthesized from the reaction of free base with ZnCl2 and fully characterized by variable temperature NMR, 2D NMR, and single crystal X-ray diffraction studies.

KW - Core-Modified Porphyrin

KW - Oxaporphyrin

KW - Porphyrin Synthesis

KW - X-ray structure

KW - Zinc Porphyrin

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U2 - 10.1016/j.tet.2011.04.034

DO - 10.1016/j.tet.2011.04.034

M3 - Article

AN - SCOPUS:79957770501

SN - 0040-4020

VL - 67

SP - 4680

EP - 4688

JO - Tetrahedron

JF - Tetrahedron

IS - 25

ER -

Toward carboxylate group functionalized A4, A2B 2, A3B oxaporphyrins and zinc complex of oxaporphyrins

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 809694: Experimental Crystal Structure Determination

引用此

Toward carboxylate group functionalized A₄, A₂B ₂, A₃B oxaporphyrins and zinc complex of oxaporphyrins