摘要
Series of new oxaporphyrins were isolated from the reaction of furan-1,4-diol, pyrrole, and an aldehyde under Lindsey's conditions, which gives easy access to ester group functionalized oxaporphyrins. The ester substituents can be readily hydrolyzed to terminal carboxylic acid in the presence of KOH. The Zn(II) oxaporphyrins have been synthesized from the reaction of free base with ZnCl2 and fully characterized by variable temperature NMR, 2D NMR, and single crystal X-ray diffraction studies.
原文 | 英語 |
---|---|
頁(從 - 到) | 4680-4688 |
頁數 | 9 |
期刊 | Tetrahedron |
卷 | 67 |
發行號 | 25 |
DOIs | |
出版狀態 | 已發佈 - 2011 6月 24 |
ASJC Scopus subject areas
- 生物化學
- 藥物發現
- 有機化學
指紋
深入研究「Toward carboxylate group functionalized A4, A2B 2, A3B oxaporphyrins and zinc complex of oxaporphyrins」主題。共同形成了獨特的指紋。資料集
-
CCDC 809694: Experimental Crystal Structure Determination
Ambre, R. (Creator), Yu, C.-Y. (Creator), Mane, S. B. (Creator), Yao, C.-F. (Creator) & Hung, C.-H. (Creator), Unknown Publisher, 2011
DOI: 10.5517/ccw5k5r, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw5k5r&sid=DataCite
資料集: Dataset