Thioiminium and thiaphospholanium derived from acetonitrile via nickel(II)-(2-mercaptophenyl)phosphine complexation

Hao Ching Chang; Yu Chen Hsu; Chia Hui Chen; Ting Shen Kuo; Way Zen Lee

doi:10.1039/c5dt03316k

Thioiminium and thiaphospholanium derived from acetonitrile via nickel(II)-(2-mercaptophenyl)phosphine complexation

Hao Ching Chang, Yu Chen Hsu, Chia Hui Chen, Ting Shen Kuo, Way Zen Lee^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

5 引文斯高帕斯（Scopus）

摘要

[Ni(P(o-C₆H₄S)(o-C₆H₄SC(CH₃)NH₂)(C₆H₅))₂](ClO₄)₂ (2) with two thioiminium functionalities is derived from CH₃CN solvent under anhydrous conditions. Moreover, thiaphospholanium salts, [(C₆H₅)P(C₆H₄SC(CH₃)(NHCOCH₃))(o-C₆H₄SH)](ClO₄) (3) and [(C₆H₅)₂-P(C₆H₄SC(CH₃)(NH₃))](ClO₄)₂ (5), can be obtained through a similar Pinner-type nitrile activation. These results demonstrate the possible intermediate of enzymatic nitrile transformation and also provide an approach to the preparation of 2-amino-1,3-benzothiaphospholanium derivatives.

原文	英語
頁（從 - 到）	20808-20811
頁數	4
期刊	Dalton Transactions
卷	44
發行號	48
DOIs	https://doi.org/10.1039/c5dt03316k
出版狀態	已發佈 - 2015

ASJC Scopus subject areas

無機化學

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10.1039/c5dt03316k

其它文件與鏈接

CCDC 1420690: Experimental Crystal Structure Determination
Chang, H. (Contributor), Hsu, Y. (Contributor), Chen, C. (Contributor), Kuo, T. (Contributor) & Lee, W. (Contributor), Unknown Publisher, 2015
DOI: 10.5517/cc1jpbq8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1jpbq8&sid=DataCite
資料集: Dataset
CCDC 1420692: Experimental Crystal Structure Determination
Chang, H. (Creator), Hsu, Y. (Creator), Chen, C. (Creator), Kuo, T. (Creator) & Lee, W. (Creator), Unknown Publisher, 2015
DOI: 10.5517/cc1jpbsb, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1jpbsb&sid=DataCite
資料集: Dataset
CCDC 1420691: Experimental Crystal Structure Determination
Chang, H. (Creator), Hsu, Y. (Creator), Chen, C. (Creator), Kuo, T. (Creator) & Lee, W. (Creator), Unknown Publisher, 2015
DOI: 10.5517/cc1jpbr9, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1jpbr9&sid=DataCite
資料集: Dataset

引用此

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title = "Thioiminium and thiaphospholanium derived from acetonitrile via nickel(II)-(2-mercaptophenyl)phosphine complexation",

abstract = "[Ni(P(o-C6H4S)(o-C6H4SC(CH3)NH2)(C6H5))2](ClO4)2 (2) with two thioiminium functionalities is derived from CH3CN solvent under anhydrous conditions. Moreover, thiaphospholanium salts, [(C6H5)P(C6H4SC(CH3)(NHCOCH3))(o-C6H4SH)](ClO4) (3) and [(C6H5)2-P(C6H4SC(CH3)(NH3))](ClO4)2 (5), can be obtained through a similar Pinner-type nitrile activation. These results demonstrate the possible intermediate of enzymatic nitrile transformation and also provide an approach to the preparation of 2-amino-1,3-benzothiaphospholanium derivatives.",

author = "Chang, {Hao Ching} and Hsu, {Yu Chen} and Chen, {Chia Hui} and Kuo, {Ting Shen} and Lee, {Way Zen}",

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year = "2015",

doi = "10.1039/c5dt03316k",

language = "English",

volume = "44",

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journal = "Dalton Transactions",

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T1 - Thioiminium and thiaphospholanium derived from acetonitrile via nickel(II)-(2-mercaptophenyl)phosphine complexation

AU - Chang, Hao Ching

AU - Hsu, Yu Chen

AU - Chen, Chia Hui

AU - Kuo, Ting Shen

AU - Lee, Way Zen

PY - 2015

Y1 - 2015

N2 - [Ni(P(o-C6H4S)(o-C6H4SC(CH3)NH2)(C6H5))2](ClO4)2 (2) with two thioiminium functionalities is derived from CH3CN solvent under anhydrous conditions. Moreover, thiaphospholanium salts, [(C6H5)P(C6H4SC(CH3)(NHCOCH3))(o-C6H4SH)](ClO4) (3) and [(C6H5)2-P(C6H4SC(CH3)(NH3))](ClO4)2 (5), can be obtained through a similar Pinner-type nitrile activation. These results demonstrate the possible intermediate of enzymatic nitrile transformation and also provide an approach to the preparation of 2-amino-1,3-benzothiaphospholanium derivatives.

AB - [Ni(P(o-C6H4S)(o-C6H4SC(CH3)NH2)(C6H5))2](ClO4)2 (2) with two thioiminium functionalities is derived from CH3CN solvent under anhydrous conditions. Moreover, thiaphospholanium salts, [(C6H5)P(C6H4SC(CH3)(NHCOCH3))(o-C6H4SH)](ClO4) (3) and [(C6H5)2-P(C6H4SC(CH3)(NH3))](ClO4)2 (5), can be obtained through a similar Pinner-type nitrile activation. These results demonstrate the possible intermediate of enzymatic nitrile transformation and also provide an approach to the preparation of 2-amino-1,3-benzothiaphospholanium derivatives.

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JF - Dalton Transactions

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ER -

Thioiminium and thiaphospholanium derived from acetonitrile via nickel(II)-(2-mercaptophenyl)phosphine complexation

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 1420690: Experimental Crystal Structure Determination

CCDC 1420692: Experimental Crystal Structure Determination

CCDC 1420691: Experimental Crystal Structure Determination

引用此