The dielectric properties of La(Mg0.5Ti0.5)O 3 ceramics studied by Raman-scattering, infrared reflectivity spectroscopy, and first-principles calculations

Hsiang Lin Liu, Hung Chung Hsueh, I. Nan Lin, Ming Ti Yang, Wei Chung Lee, Yi Chun Chen, Chia Ta Chia, Hsiu Fung Cheng

研究成果: 雜誌貢獻期刊論文同行評審

6 引文 斯高帕斯(Scopus)

摘要

La(Mg0.5Ti0.5)O3 (LMT) ceramics were prepared by either the solid-state reaction (LMT)SS or the citric-acid chemical method (LMT)CA. A combination of Raman scattering, infrared reflectivity, and first-principles calculations was carried out to elucidate the correlation between lattice dynamics and the dielectric properties of these materials. Twelve Raman-active phonons are observed in both samples, displaying similar frequency positions. Interestingly, the A g phonon (g11 mode) of (LMT)SS at about 717cm-1 involving the oxygen octahedron breathing vibrations demonstrates a narrower linewidth, suggesting its better crystallinity. Furthermore, an infrared-active u2 phonon band due to the vibrations of OI and OII layers, which possesses the largest oscillator strength, exhibits stronger intensity for (LMT)SS, as compared with those for (LMT)CA. Additionally, the Q × f values (the product of dielectric Q values and measurement frequency) of (LMT) SS estimated from either microwave cavity or infrared spectroscopic measurements are larger than those of (LMT)CA. These results indicate that the better coherence of lattice vibrations in (LMT)SS leads to its higher Q × f value, providing evidence for a strong connection between optical spectroscopic behavior and microwave dielectric characteristics in these materials.

原文英語
文章編號225901
期刊Journal of Physics Condensed Matter
23
發行號22
DOIs
出版狀態已發佈 - 2011

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

指紋 深入研究「The dielectric properties of La(Mg<sub>0.5</sub>Ti<sub>0.5</sub>)O <sub>3</sub> ceramics studied by Raman-scattering, infrared reflectivity spectroscopy, and first-principles calculations」主題。共同形成了獨特的指紋。

引用此