Tetranuclear assembly of palladium(II): Catalyst for C-C coupling reactions

Poulami Pattanayak, Jahar Lal Pratihar, Debprasad Patra, Chia Her Lin, Surajit Chattopadhyay*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

15 引文 斯高帕斯(Scopus)

摘要

The 2-((2-benzylamino)phenyldiazenyl)phenol, H2OL [where H 2OL = ArOHN = NC6H4N(H)CH2(C 6H5); Ar = C6H5 (for H2OL1), p-MeC6H4 (for H2OL2) or p-ClC 6H4 (for H2OL3)], ligands were prepared by the reaction of the appropriate 2-((2-hydroxyaryl)azo)anilines with benzyl bromide. The reactions of Na2PdCl4 with H 2OL afforded tetranuclear Pd(II) complexes of the composition [Pd(OL)]4. The ligands bind palladium(II) in a tridentate (N, N, O) fashion. The X-ray structure of [Pd(OL1)]4 was determined to confirm the characterization. The newly synthesized [Pd(OL1)] 4 complex was utilized as a catalyst for the Suzuki and Heck reaction for a variety of substrates.

原文英語
頁(從 - 到)133-138
頁數6
期刊Polyhedron
63
DOIs
出版狀態已發佈 - 2013
對外發佈

ASJC Scopus subject areas

  • 物理與理論化學
  • 無機化學
  • 材料化學

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