Synthesis, X-ray structure and catecholase activity of an antiferromagnetically coupled trinuclear nickel(II) complex

Abhijit Pal, Sarat Chandra Kumar, Ayon Kanti Ghosh, Chia Her Lin, Eric Rivière, Talal Mallah, Rajarshi Ghosh*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

12 引文 斯高帕斯(Scopus)

摘要

The synthesis and X-ray crystallographic characterization of one antiferromagnetically coupled trinuclear Ni(II) complex, [Ni3(L)2(OAc)2] (1) [L = N,N-(salicyaldene)-1,3-diaminopropan-2-ol], is reported. It effectively catalyses the oxidation of 3,5-ditertiarybutyl catechol to its corresponding quinone in methanol solvent. It follows Michaelis-Menten kinetics with a turnover number of 3.85 × 103 h-1.

原文英語
頁(從 - 到)221-226
頁數6
期刊Polyhedron
110
DOIs
出版狀態已發佈 - 2016 5月 28
對外發佈

ASJC Scopus subject areas

  • 物理與理論化學
  • 無機化學
  • 材料化學

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