Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex

Sunit Kumar; Way Zen Lee; Mangalampalli Ravikanth

doi:10.1021/acs.orglett.7b03715

Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex

Sunit Kumar, Way Zen Lee, Mangalampalli Ravikanth^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

29 引文斯高帕斯（Scopus）

摘要

An unprecedented tellurabenziporphyrin containing C, N, and Te donor atoms was synthesized by condensing benzitripyrrane and tellurophene diol under acid catalyzed conditions. The tellurabenziporphyrin readily forms a Pd(II) complex when treated with PdCl₂ in CHCl₃/CH₃CN. The crystal structures of tellurabenziporphyrin and its Pd(II) complex revealed that the benzene ring hinders the π-electron delocalization. An unusual five-membered ring formed inside the macrocycle due to the strong interaction between "Te" and "N" in the Pd(II) complex.

原文	英語
頁（從 - 到）	636-639
頁數	4
期刊	Organic Letters
卷	20
發行號	3
DOIs	https://doi.org/10.1021/acs.orglett.7b03715
出版狀態	已發佈 - 2018 2月 2

ASJC Scopus subject areas

生物化學
物理與理論化學
有機化學

存取文件

10.1021/acs.orglett.7b03715

其它文件與鏈接

CCDC 1588214: Experimental Crystal Structure Determination
Kumar, S. (Creator), Lee, W. (Creator) & Ravikanth, M. (Creator), Unknown Publisher, 2018
DOI: 10.5517/ccdc.csd.cc1q9nqd, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1q9nqd&sid=DataCite
資料集: Dataset
CCDC 1588213: Experimental Crystal Structure Determination
Kumar, S. (Creator), Lee, W. (Creator) & Ravikanth, M. (Creator), Unknown Publisher, 2018
DOI: 10.5517/ccdc.csd.cc1q9npc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1q9npc&sid=DataCite
資料集: Dataset

引用此

@article{9df6ef7395fd42af92e1ebc60083628e,

title = "Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex",

abstract = "An unprecedented tellurabenziporphyrin containing C, N, and Te donor atoms was synthesized by condensing benzitripyrrane and tellurophene diol under acid catalyzed conditions. The tellurabenziporphyrin readily forms a Pd(II) complex when treated with PdCl2 in CHCl3/CH3CN. The crystal structures of tellurabenziporphyrin and its Pd(II) complex revealed that the benzene ring hinders the π-electron delocalization. An unusual five-membered ring formed inside the macrocycle due to the strong interaction between {"}Te{"} and {"}N{"} in the Pd(II) complex.",

author = "Sunit Kumar and Lee, {Way Zen} and Mangalampalli Ravikanth",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = feb,

day = "2",

doi = "10.1021/acs.orglett.7b03715",

language = "English",

volume = "20",

pages = "636--639",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex

AU - Kumar, Sunit

AU - Lee, Way Zen

AU - Ravikanth, Mangalampalli

PY - 2018/2/2

Y1 - 2018/2/2

N2 - An unprecedented tellurabenziporphyrin containing C, N, and Te donor atoms was synthesized by condensing benzitripyrrane and tellurophene diol under acid catalyzed conditions. The tellurabenziporphyrin readily forms a Pd(II) complex when treated with PdCl2 in CHCl3/CH3CN. The crystal structures of tellurabenziporphyrin and its Pd(II) complex revealed that the benzene ring hinders the π-electron delocalization. An unusual five-membered ring formed inside the macrocycle due to the strong interaction between "Te" and "N" in the Pd(II) complex.

AB - An unprecedented tellurabenziporphyrin containing C, N, and Te donor atoms was synthesized by condensing benzitripyrrane and tellurophene diol under acid catalyzed conditions. The tellurabenziporphyrin readily forms a Pd(II) complex when treated with PdCl2 in CHCl3/CH3CN. The crystal structures of tellurabenziporphyrin and its Pd(II) complex revealed that the benzene ring hinders the π-electron delocalization. An unusual five-membered ring formed inside the macrocycle due to the strong interaction between "Te" and "N" in the Pd(II) complex.

UR - http://www.scopus.com/inward/record.url?scp=85041573221&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85041573221&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.7b03715

DO - 10.1021/acs.orglett.7b03715

M3 - Article

C2 - 29355327

AN - SCOPUS:85041573221

SN - 1523-7060

VL - 20

SP - 636

EP - 639

JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 1588214: Experimental Crystal Structure Determination

CCDC 1588213: Experimental Crystal Structure Determination

引用此