Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex

Sunit Kumar, Way Zen Lee, Mangalampalli Ravikanth

研究成果: 雜誌貢獻文章

10 引文 (Scopus)

摘要

An unprecedented tellurabenziporphyrin containing C, N, and Te donor atoms was synthesized by condensing benzitripyrrane and tellurophene diol under acid catalyzed conditions. The tellurabenziporphyrin readily forms a Pd(II) complex when treated with PdCl2 in CHCl3/CH3CN. The crystal structures of tellurabenziporphyrin and its Pd(II) complex revealed that the benzene ring hinders the π-electron delocalization. An unusual five-membered ring formed inside the macrocycle due to the strong interaction between "Te" and "N" in the Pd(II) complex.

原文英語
頁(從 - 到)636-639
頁數4
期刊Organic Letters
20
發行號3
DOIs
出版狀態已發佈 - 2018 二月 2

指紋

Benzene
Crystal structure
Electrons
Atoms
Acids
condensing
rings
synthesis
benzene
acids
crystal structure
atoms
electrons
palladium chloride

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

引用此文

Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex. / Kumar, Sunit; Lee, Way Zen; Ravikanth, Mangalampalli.

於: Organic Letters, 卷 20, 編號 3, 02.02.2018, p. 636-639.

研究成果: 雜誌貢獻文章

Kumar, Sunit ; Lee, Way Zen ; Ravikanth, Mangalampalli. / Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex. 於: Organic Letters. 2018 ; 卷 20, 編號 3. 頁 636-639.
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abstract = "An unprecedented tellurabenziporphyrin containing C, N, and Te donor atoms was synthesized by condensing benzitripyrrane and tellurophene diol under acid catalyzed conditions. The tellurabenziporphyrin readily forms a Pd(II) complex when treated with PdCl2 in CHCl3/CH3CN. The crystal structures of tellurabenziporphyrin and its Pd(II) complex revealed that the benzene ring hinders the π-electron delocalization. An unusual five-membered ring formed inside the macrocycle due to the strong interaction between {"}Te{"} and {"}N{"} in the Pd(II) complex.",
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N2 - An unprecedented tellurabenziporphyrin containing C, N, and Te donor atoms was synthesized by condensing benzitripyrrane and tellurophene diol under acid catalyzed conditions. The tellurabenziporphyrin readily forms a Pd(II) complex when treated with PdCl2 in CHCl3/CH3CN. The crystal structures of tellurabenziporphyrin and its Pd(II) complex revealed that the benzene ring hinders the π-electron delocalization. An unusual five-membered ring formed inside the macrocycle due to the strong interaction between "Te" and "N" in the Pd(II) complex.

AB - An unprecedented tellurabenziporphyrin containing C, N, and Te donor atoms was synthesized by condensing benzitripyrrane and tellurophene diol under acid catalyzed conditions. The tellurabenziporphyrin readily forms a Pd(II) complex when treated with PdCl2 in CHCl3/CH3CN. The crystal structures of tellurabenziporphyrin and its Pd(II) complex revealed that the benzene ring hinders the π-electron delocalization. An unusual five-membered ring formed inside the macrocycle due to the strong interaction between "Te" and "N" in the Pd(II) complex.

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