Synthesis of pyrrole derivatives mediated by dicobalthexacarbonyl

Jeng Long Wang, Chuen Her Ueng, Ming Chang P. Yeh

研究成果: 雜誌貢獻文章同行評審

20 引文 斯高帕斯(Scopus)

摘要

Addition of α- and β-amino acid derivatives to the cobalt stabilized propargylic cation 2 gives dicobalthexacarbonyl complexes with an amino acid derivative at the propargyl position. Oxidation of the resulting complexes with Fe(III) produces propargyl amines 4. Intramolecular cyclization of 4 with LDA followed by oxidation of the crude product with DDQ affords pyrrole derivatives as the major products.

原文英語
頁(從 - 到)2823-2826
頁數4
期刊Tetrahedron Letters
36
發行號16
DOIs
出版狀態已發佈 - 1995 四月 17

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

指紋 深入研究「Synthesis of pyrrole derivatives mediated by dicobalthexacarbonyl」主題。共同形成了獨特的指紋。

引用此