TY - JOUR
T1 - Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source
AU - Senthil Raja, Duraisamy
AU - Pan, Chih Chiung
AU - Chen, Chia Wei
AU - Kang, Yu Hao
AU - Chen, Jiun Jen
AU - Lin, Chia Her
N1 - Funding Information:
Financial assistance received from the Bureau of Energy of the Ministry of Economic Affairs , Taiwan; Ministry of Science and Technology, Taiwan ( MOST103-2632-M-033-001-MY3 and MOST104-2113-M-033-006 ); and Chung Yuan Christian University are gratefully acknowledged.
Publisher Copyright:
© 2016 Elsevier Inc. All rights reserved.
PY - 2016/9/1
Y1 - 2016/9/1
N2 - A series of five isostructural pillared-paddlewheel MOFs, [M2(BDC)2(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.
AB - A series of five isostructural pillared-paddlewheel MOFs, [M2(BDC)2(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.
KW - DABCO
KW - Metal-organic framework
KW - Microporous material
KW - Renewable resources
KW - Solvothermal synthesis
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U2 - 10.1016/j.micromeso.2016.05.035
DO - 10.1016/j.micromeso.2016.05.035
M3 - Article
AN - SCOPUS:84975090397
VL - 231
SP - 186
EP - 191
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
SN - 1387-1811
ER -
