Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

Duraisamy Senthil Raja, Chih Chiung Pan, Chia Wei Chen, Yu Hao Kang, Jiun Jen Chen*, Chia Her Lin

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

12 引文 斯高帕斯(Scopus)

摘要

A series of five isostructural pillared-paddlewheel MOFs, [M2(BDC)2(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.

原文英語
頁(從 - 到)186-191
頁數6
期刊Microporous and Mesoporous Materials
231
DOIs
出版狀態已發佈 - 2016 9月 1
對外發佈

ASJC Scopus subject areas

  • 化學 (全部)
  • 材料科學(全部)
  • 凝聚態物理學
  • 材料力學

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