Synthesis of benzo[: A] carbazole derivatives from 3-ethylindoles by exploiting the dual character of benzoquinone as an oxidizing agent and dienophile

Chun Wei Kuo; Ashok Konala; Lyu Lin; Ting Ta Chiang; Chia Yu Huang; Tang Hao Yang; Veerababurao Kavala; Ching Fa Yao

doi:10.1039/c6cc03124b

Synthesis of benzo[: A] carbazole derivatives from 3-ethylindoles by exploiting the dual character of benzoquinone as an oxidizing agent and dienophile

Chun Wei Kuo
, Ashok Konala
, Lyu Lin
, Ting Ta Chiang
, Chia Yu Huang
, Tang Hao Yang
, Veerababurao Kavala
, Ching Fa Yao^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

50 引文斯高帕斯（Scopus）

摘要

The dual character of benzoquinone is exploited for the synthesis of benzo[a]carbazole derivatives starting from 3-ethylindole derivatives. A diene is generated in situ from the 3-ethylindole derivative with the help of benzoquinone, where it acts as an oxidizing agent. Later it serves as a dienophile and participates in a Diels-Alder reaction with the diene to afford benzo[a]carbazole derivatives.

原文	英語
頁（從 - 到）	7870-7873
頁數	4
期刊	Chemical Communications
卷	52
發行號	50
DOIs	https://doi.org/10.1039/c6cc03124b
出版狀態	已發佈 - 2016

ASJC Scopus subject areas

催化
電子、光磁材料
陶瓷和複合材料
一般化學
表面、塗料和薄膜
金屬和合金
材料化學

存取文件

10.1039/c6cc03124b

其它文件與鏈接

CCDC 1457405: Experimental Crystal Structure Determination
Kuo, C.-W. (Creator), Konala, A. (Creator), Lin, L. (Creator), Chiang, T.-T. (Creator), Huang, C.-Y. (Creator), Yang, T.-H. (Creator), Kavala, V. (Creator) & Yao, C.-F. (Creator), Unknown Publisher, 2016
DOI: 10.5517/ccdc.csd.cc1kxk23, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1kxk23&sid=DataCite
資料集: Dataset
CCDC 1457406: Experimental Crystal Structure Determination
Kuo, C.-W. (Creator), Konala, A. (Creator), Lin, L. (Creator), Chiang, T.-T. (Creator), Huang, C.-Y. (Creator), Yang, T.-H. (Creator), Kavala, V. (Creator) & Yao, C.-F. (Creator), Unknown Publisher, 2016
DOI: 10.5517/ccdc.csd.cc1kxk34, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1kxk34&sid=DataCite
資料集: Dataset

引用此

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title = "Synthesis of benzo[: A] carbazole derivatives from 3-ethylindoles by exploiting the dual character of benzoquinone as an oxidizing agent and dienophile",

abstract = "The dual character of benzoquinone is exploited for the synthesis of benzo[a]carbazole derivatives starting from 3-ethylindole derivatives. A diene is generated in situ from the 3-ethylindole derivative with the help of benzoquinone, where it acts as an oxidizing agent. Later it serves as a dienophile and participates in a Diels-Alder reaction with the diene to afford benzo[a]carbazole derivatives.",

author = "Kuo, \{Chun Wei\} and Ashok Konala and Lyu Lin and Chiang, \{Ting Ta\} and Huang, \{Chia Yu\} and Yang, \{Tang Hao\} and Veerababurao Kavala and Yao, \{Ching Fa\}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc03124b",

language = "English",

volume = "52",

pages = "7870--7873",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Synthesis of benzo[

T2 - A] carbazole derivatives from 3-ethylindoles by exploiting the dual character of benzoquinone as an oxidizing agent and dienophile

AU - Kuo, Chun Wei

AU - Konala, Ashok

AU - Lin, Lyu

AU - Chiang, Ting Ta

AU - Huang, Chia Yu

AU - Yang, Tang Hao

AU - Kavala, Veerababurao

AU - Yao, Ching Fa

PY - 2016

Y1 - 2016

N2 - The dual character of benzoquinone is exploited for the synthesis of benzo[a]carbazole derivatives starting from 3-ethylindole derivatives. A diene is generated in situ from the 3-ethylindole derivative with the help of benzoquinone, where it acts as an oxidizing agent. Later it serves as a dienophile and participates in a Diels-Alder reaction with the diene to afford benzo[a]carbazole derivatives.

AB - The dual character of benzoquinone is exploited for the synthesis of benzo[a]carbazole derivatives starting from 3-ethylindole derivatives. A diene is generated in situ from the 3-ethylindole derivative with the help of benzoquinone, where it acts as an oxidizing agent. Later it serves as a dienophile and participates in a Diels-Alder reaction with the diene to afford benzo[a]carbazole derivatives.

UR - https://www.scopus.com/pages/publications/84975092153

UR - https://www.scopus.com/pages/publications/84975092153#tab=citedBy

U2 - 10.1039/c6cc03124b

DO - 10.1039/c6cc03124b

M3 - Article

AN - SCOPUS:84975092153

SN - 1359-7345

VL - 52

SP - 7870

EP - 7873

JO - Chemical Communications

JF - Chemical Communications

IS - 50

ER -

Synthesis of benzo[: A] carbazole derivatives from 3-ethylindoles by exploiting the dual character of benzoquinone as an oxidizing agent and dienophile

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 1457405: Experimental Crystal Structure Determination

CCDC 1457406: Experimental Crystal Structure Determination

引用此