Synthesis, crystal structure and catecholase activity of [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine]

Ashis Kumar Maji; Sumitava Khan; Ayon Kanti Ghosh; Chia Her Lin; Barindra Kumar Ghosh; Rajarshi Ghosh

doi:10.1016/j.molstruc.2017.04.105

Synthesis, crystal structure and catecholase activity of [Co(SCN)₂(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine]

Ashis Kumar Maji
, Sumitava Khan
, Ayon Kanti Ghosh
, Chia Her Lin
, Barindra Kumar Ghosh
, Rajarshi Ghosh^*

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

10 引文斯高帕斯（Scopus）

摘要

Synthesis and structural characterization of a mononuclear cobalt(II) complex [Co(SCN)₂(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine] (1) is reported. Molecular geometry of the complex is found to be distorted octahedron with CoN₄S₂ chromophore. 1 is shown to respond in catecholase activity in methanol and acetonitrile. In each solvent Michaelis-Menten reaction kinetics were followed. The reaction mechanism of the catecholase activity is investigated using mass spectrometry.

原文	英語
頁（從 - 到）	489-494
頁數	6
期刊	Journal of Molecular Structure
卷	1143
DOIs	https://doi.org/10.1016/j.molstruc.2017.04.105
出版狀態	已發佈 - 2017 9月 5
對外發佈	是

ASJC Scopus subject areas

分析化學
光譜
有機化學
無機化學

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10.1016/j.molstruc.2017.04.105

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@article{d0179269f72b4f18a2ff6b3721ab3716,

title = "Synthesis, crystal structure and catecholase activity of [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine]",

abstract = "Synthesis and structural characterization of a mononuclear cobalt(II) complex [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine] (1) is reported. Molecular geometry of the complex is found to be distorted octahedron with CoN4S2 chromophore. 1 is shown to respond in catecholase activity in methanol and acetonitrile. In each solvent Michaelis-Menten reaction kinetics were followed. The reaction mechanism of the catecholase activity is investigated using mass spectrometry.",

keywords = "Catecholase activity, Cobalt, Schiff base, X-ray structure",

author = "Maji, \{Ashis Kumar\} and Sumitava Khan and Ghosh, \{Ayon Kanti\} and Lin, \{Chia Her\} and Ghosh, \{Barindra Kumar\} and Rajarshi Ghosh",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

month = sep,

day = "5",

doi = "10.1016/j.molstruc.2017.04.105",

language = "English",

volume = "1143",

pages = "489--494",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Synthesis, crystal structure and catecholase activity of [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine]

AU - Maji, Ashis Kumar

AU - Khan, Sumitava

AU - Ghosh, Ayon Kanti

AU - Lin, Chia Her

AU - Ghosh, Barindra Kumar

AU - Ghosh, Rajarshi

PY - 2017/9/5

Y1 - 2017/9/5

N2 - Synthesis and structural characterization of a mononuclear cobalt(II) complex [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine] (1) is reported. Molecular geometry of the complex is found to be distorted octahedron with CoN4S2 chromophore. 1 is shown to respond in catecholase activity in methanol and acetonitrile. In each solvent Michaelis-Menten reaction kinetics were followed. The reaction mechanism of the catecholase activity is investigated using mass spectrometry.

AB - Synthesis and structural characterization of a mononuclear cobalt(II) complex [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine] (1) is reported. Molecular geometry of the complex is found to be distorted octahedron with CoN4S2 chromophore. 1 is shown to respond in catecholase activity in methanol and acetonitrile. In each solvent Michaelis-Menten reaction kinetics were followed. The reaction mechanism of the catecholase activity is investigated using mass spectrometry.

KW - Catecholase activity

KW - Cobalt

KW - Schiff base

KW - X-ray structure

UR - https://www.scopus.com/pages/publications/85018726447

UR - https://www.scopus.com/pages/publications/85018726447#tab=citedBy

U2 - 10.1016/j.molstruc.2017.04.105

DO - 10.1016/j.molstruc.2017.04.105

M3 - Article

AN - SCOPUS:85018726447

SN - 0022-2860

VL - 1143

SP - 489

EP - 494

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

Synthesis, crystal structure and catecholase activity of [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine]

摘要

ASJC Scopus subject areas

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引用此

Synthesis, crystal structure and catecholase activity of [Co(SCN)₂(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine]