Synthesis, crystal structure and catecholase activity of [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine]

Ashis Kumar Maji, Sumitava Khan, Ayon Kanti Ghosh, Chia Her Lin, Barindra Kumar Ghosh, Rajarshi Ghosh*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

4 引文 斯高帕斯(Scopus)

摘要

Synthesis and structural characterization of a mononuclear cobalt(II) complex [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine] (1) is reported. Molecular geometry of the complex is found to be distorted octahedron with CoN4S2 chromophore. 1 is shown to respond in catecholase activity in methanol and acetonitrile. In each solvent Michaelis-Menten reaction kinetics were followed. The reaction mechanism of the catecholase activity is investigated using mass spectrometry.

原文英語
頁(從 - 到)489-494
頁數6
期刊Journal of Molecular Structure
1143
DOIs
出版狀態已發佈 - 2017 9月 5
對外發佈

ASJC Scopus subject areas

  • 分析化學
  • 光譜
  • 有機化學
  • 無機化學

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