摘要
The synthesis and crystal structures of two high valent molybdenum complexes containing trisbenzenethiolatophosphine ligands, [Mo 2(PS3)2(PS3H)] (1) and [Mo(PS3″)2] (2), where PS3 = [P(C6H4-2-S)3]3-, PS3H = [P(C6H4-2-S)2(C6H 4-2-SH)]2-, and PS3″ = [P(C6H 3-3-Me3Si-2-S)3]3-, are described. Compound 1 is a dimeric Mo(IV) species containing three PS3 ligands with an uncoordinated thiol group. An intramolecular hydrogen bonding S-H⋯S was found in the structure. Two molybdenum ions are bridged by three thiolates. The geometry can be described as two pentagonal bipyramids sharing a triangle face formed by three bridging S atoms. Compound 2 is a Mo(VI) species binding with two tetradentate PS3″ ligands. The eight-coordinate molybdenum center adopts a dodecahedral geometry.
原文 | 英語 |
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頁(從 - 到) | 2149-2154 |
頁數 | 6 |
期刊 | Inorganica Chimica Acta |
卷 | 358 |
發行號 | 6 |
DOIs | |
出版狀態 | 已發佈 - 2005 3月 30 |
ASJC Scopus subject areas
- 物理與理論化學
- 無機化學
- 材料化學
指紋
深入研究「Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands」主題。共同形成了獨特的指紋。資料集
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CCDC 255991: Experimental Crystal Structure Determination
Hsu, H.-F. (Creator), Peng, W.-Y. (Creator), Li, Z.-Y. (Creator), Wu, R.-R. (Creator), Liao, J.-H. (Creator), Wang, Y. (Creator), Liu, Y.-H. (Creator), Shieh, M. (Creator) & Kuo, T.-S. (Creator), Unknown Publisher, 2005
DOI: 10.5517/cc8lcsz, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8lcsz&sid=DataCite
資料集: Dataset
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CCDC 255990: Experimental Crystal Structure Determination
Hsu, H.-F. (Creator), Peng, W.-Y. (Creator), Li, Z.-Y. (Creator), Wu, R.-R. (Creator), Liao, J.-H. (Creator), Wang, Y. (Creator), Liu, Y.-H. (Creator), Shieh, M. (Creator) & Kuo, T.-S. (Creator), Unknown Publisher, 2005
DOI: 10.5517/cc8lcry, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8lcry&sid=DataCite
資料集: Dataset