Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands

Hua Fen Hsu*, Wan Yu Peng, Zung Ying Li, Ru Rong Wu, Ju Hsiou Liao, Yu Wang, Yi Hung Liu, Minghuey Shieh, Ting Shen Kuo

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

4 引文 斯高帕斯(Scopus)

摘要

The synthesis and crystal structures of two high valent molybdenum complexes containing trisbenzenethiolatophosphine ligands, [Mo 2(PS3)2(PS3H)] (1) and [Mo(PS3″)2] (2), where PS3 = [P(C6H4-2-S)3]3-, PS3H = [P(C6H4-2-S)2(C6H 4-2-SH)]2-, and PS3″ = [P(C6H 3-3-Me3Si-2-S)3]3-, are described. Compound 1 is a dimeric Mo(IV) species containing three PS3 ligands with an uncoordinated thiol group. An intramolecular hydrogen bonding S-H⋯S was found in the structure. Two molybdenum ions are bridged by three thiolates. The geometry can be described as two pentagonal bipyramids sharing a triangle face formed by three bridging S atoms. Compound 2 is a Mo(VI) species binding with two tetradentate PS3″ ligands. The eight-coordinate molybdenum center adopts a dodecahedral geometry.

原文英語
頁(從 - 到)2149-2154
頁數6
期刊Inorganica Chimica Acta
358
發行號6
DOIs
出版狀態已發佈 - 2005 3月 30

ASJC Scopus subject areas

  • 物理與理論化學
  • 無機化學
  • 材料化學

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