Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI

Paul Knochel; Ming Chang P. Yeh; Scott C. Berk; Jason Talbert

doi:10.1021/jo00245a057

Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI

Paul Knochel^*
, Ming Chang P. Yeh
, Scott C. Berk
, Jason Talbert

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

669 引文斯高帕斯（Scopus）

摘要

The new and highly functionalized copper reagents RCu(CN)ZnI obtained from readily available primary and secondary alkylzinc iodides by a transmetalation in THF with the soluble salt, CuCN-2LiX, react in good yields with acyl chlorides and enones, respectively, to afford ketones and 1,4-addition products.

原文	英語
頁（從 - 到）	2390-2392
頁數	3
期刊	Journal of Organic Chemistry
卷	53
發行號	10
DOIs	https://doi.org/10.1021/jo00245a057
出版狀態	已發佈 - 1988 2月 1
對外發佈	是

ASJC Scopus subject areas

有機化學

存取文件

10.1021/jo00245a057

其它文件與鏈接

引用此

@article{9ba4ff4fb2d0419fab990ca3cbf18c57,

title = "Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI",

abstract = "The new and highly functionalized copper reagents RCu(CN)ZnI obtained from readily available primary and secondary alkylzinc iodides by a transmetalation in THF with the soluble salt, CuCN-2LiX, react in good yields with acyl chlorides and enones, respectively, to afford ketones and 1,4-addition products.",

author = "Paul Knochel and Yeh, \{Ming Chang P.\} and Berk, \{Scott C.\} and Jason Talbert",

year = "1988",

month = feb,

day = "1",

doi = "10.1021/jo00245a057",

language = "English",

volume = "53",

pages = "2390--2392",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI

AU - Knochel, Paul

AU - Yeh, Ming Chang P.

AU - Berk, Scott C.

AU - Talbert, Jason

PY - 1988/2/1

Y1 - 1988/2/1

N2 - The new and highly functionalized copper reagents RCu(CN)ZnI obtained from readily available primary and secondary alkylzinc iodides by a transmetalation in THF with the soluble salt, CuCN-2LiX, react in good yields with acyl chlorides and enones, respectively, to afford ketones and 1,4-addition products.

AB - The new and highly functionalized copper reagents RCu(CN)ZnI obtained from readily available primary and secondary alkylzinc iodides by a transmetalation in THF with the soluble salt, CuCN-2LiX, react in good yields with acyl chlorides and enones, respectively, to afford ketones and 1,4-addition products.

UR - https://www.scopus.com/pages/publications/33845280673

UR - https://www.scopus.com/pages/publications/33845280673#tab=citedBy

U2 - 10.1021/jo00245a057

DO - 10.1021/jo00245a057

M3 - Article

AN - SCOPUS:33845280673

SN - 0022-3263

VL - 53

SP - 2390

EP - 2392

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 10

ER -

Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

引用此