Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI

Paul Knochel; Ming Chang P. Yeh; Scott C. Berk; Jason Talbert

doi:10.1021/jo00245a057

Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI

Paul Knochel^*, Ming Chang P. Yeh, Scott C. Berk, Jason Talbert

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研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

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摘要

The new and highly functionalized copper reagents RCu(CN)ZnI obtained from readily available primary and secondary alkylzinc iodides by a transmetalation in THF with the soluble salt, CuCN-2LiX, react in good yields with acyl chlorides and enones, respectively, to afford ketones and 1,4-addition products.

原文	英語
頁（從 - 到）	2390-2392
頁數	3
期刊	Journal of Organic Chemistry
卷	53
發行號	10
DOIs	https://doi.org/10.1021/jo00245a057
出版狀態	已發佈 - 1988 2月 1
對外發佈	是

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有機化學

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10.1021/jo00245a057

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title = "Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI",

abstract = "The new and highly functionalized copper reagents RCu(CN)ZnI obtained from readily available primary and secondary alkylzinc iodides by a transmetalation in THF with the soluble salt, CuCN-2LiX, react in good yields with acyl chlorides and enones, respectively, to afford ketones and 1,4-addition products.",

author = "Paul Knochel and Yeh, {Ming Chang P.} and Berk, {Scott C.} and Jason Talbert",

year = "1988",

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AU - Talbert, Jason

PY - 1988/2/1

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N2 - The new and highly functionalized copper reagents RCu(CN)ZnI obtained from readily available primary and secondary alkylzinc iodides by a transmetalation in THF with the soluble salt, CuCN-2LiX, react in good yields with acyl chlorides and enones, respectively, to afford ketones and 1,4-addition products.

AB - The new and highly functionalized copper reagents RCu(CN)ZnI obtained from readily available primary and secondary alkylzinc iodides by a transmetalation in THF with the soluble salt, CuCN-2LiX, react in good yields with acyl chlorides and enones, respectively, to afford ketones and 1,4-addition products.

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Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI

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