Synthesis and Reactivity toward Acyl Chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI

Paul Knochel, Ming Chang P. Yeh, Scott C. Berk, Jason Talbert

研究成果: 雜誌貢獻文章同行評審

604 引文 斯高帕斯(Scopus)

摘要

The new and highly functionalized copper reagents RCu(CN)ZnI obtained from readily available primary and secondary alkylzinc iodides by a transmetalation in THF with the soluble salt, CuCN-2LiX, react in good yields with acyl chlorides and enones, respectively, to afford ketones and 1,4-addition products.

原文英語
頁(從 - 到)2390-2392
頁數3
期刊Journal of Organic Chemistry
53
發行號10
DOIs
出版狀態已發佈 - 1988 二月 1

ASJC Scopus subject areas

  • Organic Chemistry

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