Synthesis and characterization of tungsten bis-imido complexes containing bi-dentate pyrrole-amine, pyrrole-imine or ketiminate ligands

Ching Sheng Hsiao, Hui Shan Chen, Shu Ya Hsu, Ting Yin Wang, Amitabha Datta, Chia Her Lin, Jui Hsien Huang*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

4 引文 斯高帕斯(Scopus)

摘要

Three new imido tungsten derivatives containing bi-dentate pyrrole-amine, pyrrole-imine or ketiminate precursor were synthesized and characterized. Reacting W(NtBu)2(NHtBu)2 with two equiv of C4H3NH(2-CH2NHtBu) and C4H3NH(2-CHNCH2Py) in diethyl ether and toluene generates [W(NtBu)2{C4H3N(2-CH 2NHtBu)}2] (1) and [W(NtBu) 2{C4H3N(2-CHNCH2Py)}2] (2) in good yield. Similarly, while subjecting two equiv of (ArNCMeCHCMeOH) (Ar = 2-MeOC6H4) with W(NtBu)2(NH tBu)2 in diethyl ether, affords [W(NtBu) 2{OCMeCHCMeNAr}2] (3) in high yield. Single crystal X-ray structure reveals that in all three complexes the 6-coordinate W atoms belong to a distorted octahedral environment.

原文英語
頁(從 - 到)1-5
頁數5
期刊Inorganica Chimica Acta
413
DOIs
出版狀態已發佈 - 2014 3月 24
對外發佈

ASJC Scopus subject areas

  • 物理與理論化學
  • 無機化學
  • 材料化學

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