Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

Chia Chun Chen; Rai Shung Liu

doi:10.1016/0022-328X(87)87172-3

Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

Chia Chun Chen^*
, Rai Shung Liu

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

1 引文斯高帕斯（Scopus）

摘要

1-Halopen-2,4-dienes CH₂CHCHCHCH₂X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR₃)₂ (M = Rh, PR₃ = PMe₂Ph; M = Ir, PR₃ = PMe₂Ph, PPh₃). The configurations of these adducts were elucidated by combining their far-IR, ¹H and ³¹P NMR spectra.

原文	英語
頁（從 - 到）	249-255
頁數	7
期刊	Journal of Organometallic Chemistry
卷	336
發行號	1-2
DOIs	https://doi.org/10.1016/0022-328X(87)87172-3
出版狀態	已發佈 - 1987 12月 8
對外發佈	是

ASJC Scopus subject areas

生物化學
物理與理論化學
有機化學
無機化學
材料化學

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10.1016/0022-328X(87)87172-3

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title = "Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes",

abstract = "1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.",

author = "Chen, \{Chia Chun\} and Liu, \{Rai Shung\}",

year = "1987",

month = dec,

day = "8",

doi = "10.1016/0022-328X(87)87172-3",

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pages = "249--255",

journal = "Journal of Organometallic Chemistry",

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T1 - Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

AU - Chen, Chia Chun

AU - Liu, Rai Shung

PY - 1987/12/8

Y1 - 1987/12/8

N2 - 1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.

AB - 1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.

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U2 - 10.1016/0022-328X(87)87172-3

DO - 10.1016/0022-328X(87)87172-3

M3 - Article

AN - SCOPUS:45949113892

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VL - 336

SP - 249

EP - 255

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

摘要

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