TY - JOUR
T1 - Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes
AU - Chen, Chia Chun
AU - Liu, Rai Shung
PY - 1987/12/8
Y1 - 1987/12/8
N2 - 1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.
AB - 1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.
UR - http://www.scopus.com/inward/record.url?scp=45949113892&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=45949113892&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(87)87172-3
DO - 10.1016/0022-328X(87)87172-3
M3 - Article
AN - SCOPUS:45949113892
SN - 0022-328X
VL - 336
SP - 249
EP - 255
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-2
ER -