Syntheses, structures, and properties of multidimensional lithium coordination polymers based on aliphatic carboxylic acids

Pei Chi Cheng, Wei Cheng Lin, Feng Shuen Tseng, Ching Che Kao, Ting Guang Chang, Duraisamy Senthil Raja, Wei Ren Liu*, Chia Her Lin

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

19 引文 斯高帕斯(Scopus)

摘要

Three lithium coordination polymers, [Li4(H2O) 2(EDTA)] (1), [Li4(H2O)4(BTCA)] (2), and (H2NMe2)2[Li2(H 2O)2(BTCA)] (3) (H4EDTA = ethylenediaminetetraacetic acid, H4BTCA = 1,2,3,4-butane tetracarboxylic acid, H2NMe2 = dimethyl amine), have been synthesized by reacting lithium salts with aliphatic carboxylic acids using a solvothermal method. The structures of all the three complexes have been determined by single crystal X-ray diffraction studies. The single crystal structure analysis revealed that complex 1 has a three-dimensional framework, whereas complex 2 has 2D sheets and complex 3 has 1D chains. In addition, these lithium complexes contain various inorganic motifs with a tetramer in 1 and 2, and discrete tetrahedra in 3 and have further been connected through organic ligands to construct multidimensional structures. Further, the electrochemical properties of complexes 1-3 have been studied to evaluate these compounds as electrode materials for lithium ion batteries with discharge capacities of around 100 mA h g-1 in the first thirty cycles.

原文英語
頁(從 - 到)2765-2772
頁數8
期刊Dalton Transactions
42
發行號8
DOIs
出版狀態已發佈 - 2013 2月 28
對外發佈

ASJC Scopus subject areas

  • 無機化學

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