Syntheses of chromium pentacarbonyl derivatives of arsenic(V) and antimony(V). Contrasting chemical reactivity with organic halogen derivatives

J. J. Cherng; Y. W. Lai; Y. H. Liu; S. M. Peng; C. H. Ueng; M. Shieh

doi:10.1021/ic0004277

Syntheses of chromium pentacarbonyl derivatives of arsenic(V) and antimony(V). Contrasting chemical reactivity with organic halogen derivatives

J. J. Cherng, Y. W. Lai, Y. H. Liu, S. M. Peng, C. H. Ueng, M. Shieh^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

15 引文斯高帕斯（Scopus）

摘要

We have synthesized a new series of chromium-group 15 dihydride and hydride complexes [H₂As{Cr(CO)₅}₂]^- (1) and [HE{Cr(CO)₅}₃]^2- (E = As, 2a; E = Sb, 2b), which represent the first examples of group 6 complexes containing E-H fragments. The contrasting chemical reactivity of 2a and 2b with organic halogen derivatives is demonstrated. The reaction of 2a with RBr (R = PhCH₂, HC≡CCH₂) produces the RX addition products [(R)(Br)As{Cr(CO)₅}₂]^- (R = PhCH₂, 3; R = C₃H₃, 4), while the treatment of 2b with RX (RX = PhCH₂Br or HC≡CCH₂Br, CH₃(CH₂)₅C(O)CI) forms the halo-substituted complexes [XSb{Cr(CO)₅}₃]^2- (X = Br, 5; X = Cl, 6). Moreover, the dihaloantimony complexes [XX′Sb{Cr(CO)₅}₂]^- can be obtained from the reaction of 2b with the appropriate organic halides. In this study, a series of organoarsenic and antimony chromium carbonyl complexes have been synthesized and structurally characterized and the role of the main group on the formation of the resultant complexes is also discussed.

原文	英語
頁（從 - 到）	1206-1212
頁數	7
期刊	Inorganic Chemistry
卷	40
發行號	6
DOIs	https://doi.org/10.1021/ic0004277
出版狀態	已發佈 - 2001 3月 12

ASJC Scopus subject areas

物理與理論化學
無機化學

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10.1021/ic0004277

其它文件與鏈接

CCDC 161535: Experimental Crystal Structure Determination
Cherng, J. (Creator), Lai, Y. (Creator), Liu, Y. (Creator), Peng, S. (Creator), Ueng, C. (Creator) & Shieh, M. (Creator), Unknown Publisher, 2001
DOI: 10.5517/cc5f2tg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc5f2tg&sid=DataCite
資料集: Dataset
CCDC 161533: Experimental Crystal Structure Determination
Cherng, J. (Creator), Lai, Y. (Creator), Liu, Y. (Creator), Peng, S. (Creator), Ueng, C. (Creator) & Shieh, M. (Creator), Unknown Publisher, 2001
DOI: 10.5517/cc5f2rd, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc5f2rd&sid=DataCite
資料集: Dataset
CCDC 161538: Experimental Crystal Structure Determination
Cherng, J. (Creator), Lai, Y. (Creator), Liu, Y. (Creator), Peng, S. (Creator), Ueng, C. (Creator) & Shieh, M. (Creator), Unknown Publisher, 2001
DOI: 10.5517/cc5f2xk, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc5f2xk&sid=DataCite
資料集: Dataset

引用此

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title = "Syntheses of chromium pentacarbonyl derivatives of arsenic(V) and antimony(V). Contrasting chemical reactivity with organic halogen derivatives",

abstract = "We have synthesized a new series of chromium-group 15 dihydride and hydride complexes [H2As{Cr(CO)5}2]- (1) and [HE{Cr(CO)5}3]2- (E = As, 2a; E = Sb, 2b), which represent the first examples of group 6 complexes containing E-H fragments. The contrasting chemical reactivity of 2a and 2b with organic halogen derivatives is demonstrated. The reaction of 2a with RBr (R = PhCH2, HC≡CCH2) produces the RX addition products [(R)(Br)As{Cr(CO)5}2]- (R = PhCH2, 3; R = C3H3, 4), while the treatment of 2b with RX (RX = PhCH2Br or HC≡CCH2Br, CH3(CH2)5C(O)CI) forms the halo-substituted complexes [XSb{Cr(CO)5}3]2- (X = Br, 5; X = Cl, 6). Moreover, the dihaloantimony complexes [XX′Sb{Cr(CO)5}2]- can be obtained from the reaction of 2b with the appropriate organic halides. In this study, a series of organoarsenic and antimony chromium carbonyl complexes have been synthesized and structurally characterized and the role of the main group on the formation of the resultant complexes is also discussed.",

author = "Cherng, {J. J.} and Lai, {Y. W.} and Liu, {Y. H.} and Peng, {S. M.} and Ueng, {C. H.} and M. Shieh",

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T1 - Syntheses of chromium pentacarbonyl derivatives of arsenic(V) and antimony(V). Contrasting chemical reactivity with organic halogen derivatives

AU - Cherng, J. J.

AU - Lai, Y. W.

AU - Liu, Y. H.

AU - Peng, S. M.

AU - Ueng, C. H.

AU - Shieh, M.

PY - 2001/3/12

Y1 - 2001/3/12

N2 - We have synthesized a new series of chromium-group 15 dihydride and hydride complexes [H2As{Cr(CO)5}2]- (1) and [HE{Cr(CO)5}3]2- (E = As, 2a; E = Sb, 2b), which represent the first examples of group 6 complexes containing E-H fragments. The contrasting chemical reactivity of 2a and 2b with organic halogen derivatives is demonstrated. The reaction of 2a with RBr (R = PhCH2, HC≡CCH2) produces the RX addition products [(R)(Br)As{Cr(CO)5}2]- (R = PhCH2, 3; R = C3H3, 4), while the treatment of 2b with RX (RX = PhCH2Br or HC≡CCH2Br, CH3(CH2)5C(O)CI) forms the halo-substituted complexes [XSb{Cr(CO)5}3]2- (X = Br, 5; X = Cl, 6). Moreover, the dihaloantimony complexes [XX′Sb{Cr(CO)5}2]- can be obtained from the reaction of 2b with the appropriate organic halides. In this study, a series of organoarsenic and antimony chromium carbonyl complexes have been synthesized and structurally characterized and the role of the main group on the formation of the resultant complexes is also discussed.

AB - We have synthesized a new series of chromium-group 15 dihydride and hydride complexes [H2As{Cr(CO)5}2]- (1) and [HE{Cr(CO)5}3]2- (E = As, 2a; E = Sb, 2b), which represent the first examples of group 6 complexes containing E-H fragments. The contrasting chemical reactivity of 2a and 2b with organic halogen derivatives is demonstrated. The reaction of 2a with RBr (R = PhCH2, HC≡CCH2) produces the RX addition products [(R)(Br)As{Cr(CO)5}2]- (R = PhCH2, 3; R = C3H3, 4), while the treatment of 2b with RX (RX = PhCH2Br or HC≡CCH2Br, CH3(CH2)5C(O)CI) forms the halo-substituted complexes [XSb{Cr(CO)5}3]2- (X = Br, 5; X = Cl, 6). Moreover, the dihaloantimony complexes [XX′Sb{Cr(CO)5}2]- can be obtained from the reaction of 2b with the appropriate organic halides. In this study, a series of organoarsenic and antimony chromium carbonyl complexes have been synthesized and structurally characterized and the role of the main group on the formation of the resultant complexes is also discussed.

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Syntheses of chromium pentacarbonyl derivatives of arsenic(V) and antimony(V). Contrasting chemical reactivity with organic halogen derivatives

摘要

ASJC Scopus subject areas

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指紋

資料集

CCDC 161535: Experimental Crystal Structure Determination

CCDC 161533: Experimental Crystal Structure Determination

CCDC 161538: Experimental Crystal Structure Determination

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