Study on the Nucleophilic Addition to (η4‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex

Ming‐Chang P. Yeh; Chih‐Hong ‐H Chu; Mei‐Ling ‐L Sun; Kuo‐Ping ‐P Kang

doi:10.1002/jccs.199000075

Study on the Nucleophilic Addition to (η⁴‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex

Ming‐Chang P. Yeh^*
, Chih‐Hong ‐H Chu
, Mei‐Ling ‐L Sun
, Kuo‐Ping ‐P Kang

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

8 引文斯高帕斯（Scopus）

摘要

Reaction of the reactive carbanion with (η⁴‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27%) together with the regular C‐2 adduct (71%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.

原文	英語
頁（從 - 到）	547-556
頁數	10
期刊	Journal of the Chinese Chemical Society
卷	37
發行號	6
DOIs	https://doi.org/10.1002/jccs.199000075
出版狀態	已發佈 - 1990 12月
對外發佈	是

ASJC Scopus subject areas

一般化學

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10.1002/jccs.199000075

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title = "Study on the Nucleophilic Addition to (η4‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex",

abstract = "Reaction of the reactive carbanion with (η4‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27\%) together with the regular C‐2 adduct (71\%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.",

keywords = "CO insertion, Cine substitution, Reductive elimination, a‐methoxy elimination, p‐hydride elimination",

author = "Yeh, \{Ming‐Chang P.\} and Chu, \{Chih‐Hong ‐H\} and Sun, \{Mei‐Ling ‐L\} and Kang, \{Kuo‐Ping ‐P\}",

year = "1990",

month = dec,

doi = "10.1002/jccs.199000075",

language = "English",

volume = "37",

pages = "547--556",

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TY - JOUR

T1 - Study on the Nucleophilic Addition to (η4‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex

AU - Yeh, Ming‐Chang P.

AU - Chu, Chih‐Hong ‐H

AU - Sun, Mei‐Ling ‐L

AU - Kang, Kuo‐Ping ‐P

PY - 1990/12

Y1 - 1990/12

N2 - Reaction of the reactive carbanion with (η4‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27%) together with the regular C‐2 adduct (71%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.

AB - Reaction of the reactive carbanion with (η4‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27%) together with the regular C‐2 adduct (71%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.

KW - CO insertion

KW - Cine substitution

KW - Reductive elimination

KW - a‐methoxy elimination

KW - p‐hydride elimination

UR - https://www.scopus.com/pages/publications/84985097709

UR - https://www.scopus.com/pages/publications/84985097709#tab=citedBy

U2 - 10.1002/jccs.199000075

DO - 10.1002/jccs.199000075

M3 - Article

AN - SCOPUS:84985097709

SN - 0009-4536

VL - 37

SP - 547

EP - 556

JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

IS - 6

ER -

Study on the Nucleophilic Addition to (η4‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

引用此

Study on the Nucleophilic Addition to (η⁴‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex