Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet

Way Zen Lee; Ya Lin Kang; Tzu Li Wang; Chan Cheng Su; Ting Shen Kuo

doi:10.1021/cg8002977

Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet

Way Zen Lee^*, Ya Lin Kang, Tzu Li Wang, Chan Cheng Su, Ting Shen Kuo

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

15 引文斯高帕斯（Scopus）

摘要

Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η³-dpt) (η²-dpt)](ClO₄)₂ (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.

原文	英語
頁（從 - 到）	2614-2616
頁數	3
期刊	Crystal Growth and Design
卷	8
發行號	8
DOIs	https://doi.org/10.1021/cg8002977
出版狀態	已發佈 - 2008 8月

ASJC Scopus subject areas

一般化學
一般材料科學
凝聚態物理學

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10.1021/cg8002977

其它文件與鏈接

CCDC 703545: Experimental Crystal Structure Determination
Lee, W. (Creator), Kang, Y. (Creator), Wang, T. (Creator), Su, C. (Creator) & Kuo, T. (Creator), Unknown Publisher, 2009
DOI: 10.5517/ccrm30g, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrm30g&sid=DataCite
資料集: Dataset
CCDC 703546: Experimental Crystal Structure Determination
Lee, W. (Creator), Kang, Y. (Creator), Wang, T. (Creator), Su, C. (Creator) & Kuo, T. (Creator), Unknown Publisher, 2009
DOI: 10.5517/ccrm31h, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrm31h&sid=DataCite
資料集: Dataset

引用此

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title = "Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet",

abstract = "Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.",

author = "Lee, {Way Zen} and Kang, {Ya Lin} and Wang, {Tzu Li} and Su, {Chan Cheng} and Kuo, {Ting Shen}",

year = "2008",

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doi = "10.1021/cg8002977",

language = "English",

volume = "8",

pages = "2614--2616",

journal = "Crystal Growth and Design",

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T1 - Structural interconversion controlled by hydrogen-bond interactions

T2 - A mononuclear copper triamine complex and a polynuclear copper triamine sheet

AU - Lee, Way Zen

AU - Kang, Ya Lin

AU - Wang, Tzu Li

AU - Su, Chan Cheng

AU - Kuo, Ting Shen

PY - 2008/8

Y1 - 2008/8

N2 - Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.

AB - Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.

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JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 8

ER -

Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 703545: Experimental Crystal Structure Determination

CCDC 703546: Experimental Crystal Structure Determination

引用此