Structural determination of ruthenium complexes containing bi-dentate pyrrole-ketone ligands

Ya Wen Tsai; Yun Fan Chen; Yong Jie Li; Kuan Hung Chen; Chia Her Lin; Jui Hsien Huang

doi:10.3390/molecules23010159

Structural determination of ruthenium complexes containing bi-dentate pyrrole-ketone ligands

Ya Wen Tsai
, Yun Fan Chen
, Yong Jie Li
, Kuan Hung Chen
, Chia Her Lin
, Jui Hsien Huang^*

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

4 引文斯高帕斯（Scopus）

摘要

A series of ruthenium compounds containing a pyrrole-ketone bidentate ligand, 2-(2-methoxybenzoyl)pyrrole (1), have been synthesized and characterized. Reacting 1 with [(η⁶-cymene)RuCl₂]₂ and RuHCl(CO)(PPh₃)₃ generated Ru(η⁶-cymene)[C₄H₃N-2-(CO-C₆H₄-2-OMe)]Cl (2) and {RuCl(CO)(PPh₃)₂[C₄H₃N-2-(COC₆H₄-2-OMe)]} (3), respectively, in moderate yields. Successively reacting 2 with sodium cyanate and sodium azide gave {Ru(η⁶-cymene)[C₄H₃N-2-(CO-C₆H₄-2-OMe)]X} (4, X=OCN; 5, X=N₃) with the elimination of sodium chloride. Compounds 2–5 were all characterized by¹H and¹³C-NMR spectra and their structures were also determined by X-ray single crystallography.

原文	英語
文章編號	159
期刊	Molecules
卷	23
發行號	1
DOIs	https://doi.org/10.3390/molecules23010159
出版狀態	已發佈 - 2018
對外發佈	是

ASJC Scopus subject areas

分析化學
化學（雜項）
分子醫學
藥學科學
藥物發現
物理與理論化學
有機化學

存取文件

10.3390/molecules23010159

其它文件與鏈接

引用此

@article{705b5ad79d8a4adfba3f84fb3bfdfb1b,

title = "Structural determination of ruthenium complexes containing bi-dentate pyrrole-ketone ligands",

abstract = "A series of ruthenium compounds containing a pyrrole-ketone bidentate ligand, 2-(2-methoxybenzoyl)pyrrole (1), have been synthesized and characterized. Reacting 1 with [(η6-cymene)RuCl2]2 and RuHCl(CO)(PPh3)3 generated Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]Cl (2) and \{RuCl(CO)(PPh3)2[C4H3N-2-(COC6H4-2-OMe)]\} (3), respectively, in moderate yields. Successively reacting 2 with sodium cyanate and sodium azide gave \{Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]X\} (4, X=OCN; 5, X=N3) with the elimination of sodium chloride. Compounds 2–5 were all characterized by1H and13C-NMR spectra and their structures were also determined by X-ray single crystallography.",

keywords = "Cymene, Pyrrole-ketone, Ruthenium, Ruthenium-hydride",

author = "Tsai, \{Ya Wen\} and Chen, \{Yun Fan\} and Li, \{Yong Jie\} and Chen, \{Kuan Hung\} and Lin, \{Chia Her\} and Huang, \{Jui Hsien\}",

note = "Publisher Copyright: 2018 by the authors.",

year = "2018",

doi = "10.3390/molecules23010159",

language = "English",

volume = "23",

journal = "Molecules",

issn = "1420-3049",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "1",

}

TY - JOUR

T1 - Structural determination of ruthenium complexes containing bi-dentate pyrrole-ketone ligands

AU - Tsai, Ya Wen

AU - Chen, Yun Fan

AU - Li, Yong Jie

AU - Chen, Kuan Hung

AU - Lin, Chia Her

AU - Huang, Jui Hsien

N1 - Publisher Copyright: 2018 by the authors.

PY - 2018

Y1 - 2018

N2 - A series of ruthenium compounds containing a pyrrole-ketone bidentate ligand, 2-(2-methoxybenzoyl)pyrrole (1), have been synthesized and characterized. Reacting 1 with [(η6-cymene)RuCl2]2 and RuHCl(CO)(PPh3)3 generated Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]Cl (2) and {RuCl(CO)(PPh3)2[C4H3N-2-(COC6H4-2-OMe)]} (3), respectively, in moderate yields. Successively reacting 2 with sodium cyanate and sodium azide gave {Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]X} (4, X=OCN; 5, X=N3) with the elimination of sodium chloride. Compounds 2–5 were all characterized by1H and13C-NMR spectra and their structures were also determined by X-ray single crystallography.

AB - A series of ruthenium compounds containing a pyrrole-ketone bidentate ligand, 2-(2-methoxybenzoyl)pyrrole (1), have been synthesized and characterized. Reacting 1 with [(η6-cymene)RuCl2]2 and RuHCl(CO)(PPh3)3 generated Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]Cl (2) and {RuCl(CO)(PPh3)2[C4H3N-2-(COC6H4-2-OMe)]} (3), respectively, in moderate yields. Successively reacting 2 with sodium cyanate and sodium azide gave {Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]X} (4, X=OCN; 5, X=N3) with the elimination of sodium chloride. Compounds 2–5 were all characterized by1H and13C-NMR spectra and their structures were also determined by X-ray single crystallography.

KW - Cymene

KW - Pyrrole-ketone

KW - Ruthenium

KW - Ruthenium-hydride

UR - https://www.scopus.com/pages/publications/85040534089

UR - https://www.scopus.com/pages/publications/85040534089#tab=citedBy

U2 - 10.3390/molecules23010159

DO - 10.3390/molecules23010159

M3 - Article

C2 - 29342833

AN - SCOPUS:85040534089

SN - 1420-3049

VL - 23

JO - Molecules

JF - Molecules

IS - 1

M1 - 159

ER -

Structural determination of ruthenium complexes containing bi-dentate pyrrole-ketone ligands

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

引用此