摘要
A series of ruthenium compounds containing a pyrrole-ketone bidentate ligand, 2-(2-methoxybenzoyl)pyrrole (1), have been synthesized and characterized. Reacting 1 with [(η6-cymene)RuCl2]2 and RuHCl(CO)(PPh3)3 generated Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]Cl (2) and {RuCl(CO)(PPh3)2[C4H3N-2-(COC6H4-2-OMe)]} (3), respectively, in moderate yields. Successively reacting 2 with sodium cyanate and sodium azide gave {Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]X} (4, X=OCN; 5, X=N3) with the elimination of sodium chloride. Compounds 2–5 were all characterized by1H and13C-NMR spectra and their structures were also determined by X-ray single crystallography.
原文 | 英語 |
---|---|
文章編號 | 159 |
期刊 | Molecules |
卷 | 23 |
發行號 | 1 |
DOIs | |
出版狀態 | 已發佈 - 2018 |
對外發佈 | 是 |
ASJC Scopus subject areas
- 分析化學
- 化學(雜項)
- 分子醫學
- 藥學科學
- 藥物發現
- 物理與理論化學
- 有機化學