Straightforward and highly efficient catalyst-free regioselective reaction of thiol to β-nitrostyrene: a concise synthesis of vinyl sulfide and nitro sulfide

Cheng Ming Chu, Zhijay Tu, Pohsi Wu, Chieh Chieh Wang, Ju Tsung Liu, Chun Wei Kuo, Yu Hsuan Shin, Ching Fa Yao*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

20 引文 斯高帕斯(Scopus)

摘要

Under catalyst-free reaction conditions, solvent-mediated addition of thiol 2 to β-nitrostyrene 1 proceeded with regioselective control to afford either adduct 3 or vinyl sulfide 4 in good to excellent yield. Thermodynamic and autocatalytic reaction mechanisms were proposed to rationalize the products thus formed.

原文英語
頁(從 - 到)3878-3885
頁數8
期刊Tetrahedron
65
發行號19
DOIs
出版狀態已發佈 - 2009 5月 9

ASJC Scopus subject areas

  • 生物化學
  • 藥物發現
  • 有機化學

指紋

深入研究「Straightforward and highly efficient catalyst-free regioselective reaction of thiol to β-nitrostyrene: a concise synthesis of vinyl sulfide and nitro sulfide」主題。共同形成了獨特的指紋。

引用此