Solvothermal syntheses and magnetic properties of two new coordination polymers with mixed ligands

Chia Her Lin*, Tai Hsing Tsao

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

7 引文 斯高帕斯(Scopus)

摘要

Two new coordination polymers, [Ni(H2O)(BDC)(bpp)]n (1) and [Co(mBDC)(bpp)]n (2) (BDC = 1,4-benzene dicarboxylate anion; bpp = 4,4′-trimethylene dipyridine; mBDC = 1,3-benzene dicarboxylate anion), were synthesized by solvothermal reaction and structurally characterized. Single crystal X-ray diffraction showed that 1 consists of an inclined interpenetration of 1D nets generating an overall 3D entanglement and compound 2 of 1D chains. The luminescent and magnetic properties of both compounds in the solid state were also investigated. Crystal data: 1: orthorhombic, Pnna; a = 18.3648(6), b = 13.6854(4), c = 16.2307(5) Å, V = 4079.3(2) Å3, and Z = 8. Crystal data: 2: triclinic, P1̄; a = 8.6966(4), b = 10.1093(4), c = 11.8334(4) Å, α = 68.263(1)°, β = 82.895(1)°, γ = 78.370(1)°, V = 945.16(7) Å3, and Z = 2.

原文英語
頁(從 - 到)1759-1764
頁數6
期刊Zeitschrift fur Anorganische und Allgemeine Chemie
634
發行號10
DOIs
出版狀態已發佈 - 2008 8月
對外發佈

ASJC Scopus subject areas

  • 無機化學

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