TY - JOUR
T1 - Small Molecule Reactions on Clean and Modified Iron Surfaces
AU - Bernasek, S. L.
AU - Lu, J. P.
AU - Albert, M. R.
AU - Hung, W. S.
N1 - Funding Information:
ACKNOWLEDGEMENTS This work was supported by the National Science Foundation, Division of Materials Research, and in its early stages by grants from Exxon Research and Engineering. Collaboration and discussion with Dr. John Gland and Dr. Dan Dwyer formerly at Exxon Research and Engineering, and with Professor Jeffrey Schwartz of Princeton University are gratefully acknowledged.
PY - 1991/1/1
Y1 - 1991/1/1
N2 - The connection between structure and reactivity in heterogeneous reactions can be best studied using model substrates whose structure can be characterized and controlled. Several examples of this approach to the understanding of structure-reactivity relationships in heterogeneous catalysis are presented, based on recent investigations of the Fe(100) surface. This surface exhibits a rich and complex chemistry, illustrated here by discussions of the adsorption and reaction of CO, O2, H2O, CH3OH and CH3SH on the clean and modified Fe(100) surface. An approach to the preparation of characterizable mixed metal oxide substrates based on the hydroxylated Fe(100) surface is also presented.
AB - The connection between structure and reactivity in heterogeneous reactions can be best studied using model substrates whose structure can be characterized and controlled. Several examples of this approach to the understanding of structure-reactivity relationships in heterogeneous catalysis are presented, based on recent investigations of the Fe(100) surface. This surface exhibits a rich and complex chemistry, illustrated here by discussions of the adsorption and reaction of CO, O2, H2O, CH3OH and CH3SH on the clean and modified Fe(100) surface. An approach to the preparation of characterizable mixed metal oxide substrates based on the hydroxylated Fe(100) surface is also presented.
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U2 - 10.1016/S0167-2991(08)61949-7
DO - 10.1016/S0167-2991(08)61949-7
M3 - Article
AN - SCOPUS:77956921057
VL - 67
SP - 315
EP - 326
JO - Studies in Surface Science and Catalysis
JF - Studies in Surface Science and Catalysis
SN - 0167-2991
IS - C
ER -