Self-complementarity of oligo-2-aminopyridines: A new class of hydrogen-bonded ladders

Man Kit Leung; Ashis B. Mandal; Chih Chieh Wang; Gene Hsiang Lee; Shie Ming Peng; Hsing Ling Cheng; Guor Rong Her; Ito Chao; Hsiu Feng Lu; Ying Chieh Sun; Mei Ying Shiao; Pi Tai Chou

doi:10.1021/ja011679p

Self-complementarity of oligo-2-aminopyridines: A new class of hydrogen-bonded ladders

Man Kit Leung, Ashis B. Mandal, Chih Chieh Wang, Gene Hsiang Lee, Shie Ming Peng, Hsing Ling Cheng, Guor Rong Her, Ito Chao, Hsiu Feng Lu, Ying Chieh Sun, Mei Ying Shiao, Pi Tai Chou^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

52 引文斯高帕斯（Scopus）

摘要

A new class of hydrogen-bonded ladders based on hydrogen-bonded dimerization of oligo-α-aminopryidines has been demonstrated. Jorgensen's model can be successfully applied to this hydrogen-bonding system in nonpolar solvents. The results show the competitive enthalpy/entropy compensation relationship upon dimerization. Although increasing the number of hydrogen-bonding interactions would enhance the hydrogen-bonding stabilization enthalpy, this stabilization enthalpy per unit would be partially sacrificed to compensate for the entropy loss due to dimerization. These results clearly support the importance of preorganization in designing hydrogen-bonding guest - host molecules.

原文	英語
頁（從 - 到）	4287-4297
頁數	11
期刊	Journal of the American Chemical Society
卷	124
發行號	16
DOIs	https://doi.org/10.1021/ja011679p
出版狀態	已發佈 - 2002 4月 24

ASJC Scopus subject areas

催化
一般化學
生物化學
膠體和表面化學

存取文件

10.1021/ja011679p

其它文件與鏈接

CCDC 149603: Experimental Crystal Structure Determination
Leung, M. (Creator), Mandal, A. B. (Creator), Wang, C. (Creator), Lee, G. (Creator), Peng, S. (Creator), Cheng, H. (Creator), Her, G. (Creator), Chao, I. (Creator), Lu, H. (Creator), Sun, Y. (Creator), Shiao, M. (Creator) & Chou, P. (Creator), Unknown Publisher, 2002
DOI: 10.5517/cc50nxq, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc50nxq&sid=DataCite
資料集: Dataset
CCDC 149601: Experimental Crystal Structure Determination
Leung, M. (Creator), Mandal, A. B. (Creator), Wang, C. (Creator), Lee, G. (Creator), Peng, S. (Creator), Cheng, H. (Creator), Her, G. (Creator), Chao, I. (Creator), Lu, H. (Creator), Sun, Y. (Creator), Shiao, M. (Creator) & Chou, P. (Creator), Unknown Publisher, 2002
DOI: 10.5517/cc50nvn, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc50nvn&sid=DataCite
資料集: Dataset
CCDC 149602: Experimental Crystal Structure Determination
Leung, M. (Creator), Mandal, A. B. (Creator), Wang, C. (Creator), Lee, G. (Creator), Peng, S. (Creator), Cheng, H. (Creator), Her, G. (Creator), Chao, I. (Creator), Lu, H. (Creator), Sun, Y. (Creator), Shiao, M. (Creator) & Chou, P. (Creator), Unknown Publisher, 2002
DOI: 10.5517/cc50nwp, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc50nwp&sid=DataCite
資料集: Dataset

引用此

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title = "Self-complementarity of oligo-2-aminopyridines: A new class of hydrogen-bonded ladders",

abstract = "A new class of hydrogen-bonded ladders based on hydrogen-bonded dimerization of oligo-α-aminopryidines has been demonstrated. Jorgensen's model can be successfully applied to this hydrogen-bonding system in nonpolar solvents. The results show the competitive enthalpy/entropy compensation relationship upon dimerization. Although increasing the number of hydrogen-bonding interactions would enhance the hydrogen-bonding stabilization enthalpy, this stabilization enthalpy per unit would be partially sacrificed to compensate for the entropy loss due to dimerization. These results clearly support the importance of preorganization in designing hydrogen-bonding guest - host molecules.",

author = "Leung, {Man Kit} and Mandal, {Ashis B.} and Wang, {Chih Chieh} and Lee, {Gene Hsiang} and Peng, {Shie Ming} and Cheng, {Hsing Ling} and Her, {Guor Rong} and Ito Chao and Lu, {Hsiu Feng} and Sun, {Ying Chieh} and Shiao, {Mei Ying} and Chou, {Pi Tai}",

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T2 - A new class of hydrogen-bonded ladders

AU - Leung, Man Kit

AU - Mandal, Ashis B.

AU - Wang, Chih Chieh

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

AU - Cheng, Hsing Ling

AU - Her, Guor Rong

AU - Chao, Ito

AU - Lu, Hsiu Feng

AU - Sun, Ying Chieh

AU - Shiao, Mei Ying

AU - Chou, Pi Tai

PY - 2002/4/24

Y1 - 2002/4/24

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AB - A new class of hydrogen-bonded ladders based on hydrogen-bonded dimerization of oligo-α-aminopryidines has been demonstrated. Jorgensen's model can be successfully applied to this hydrogen-bonding system in nonpolar solvents. The results show the competitive enthalpy/entropy compensation relationship upon dimerization. Although increasing the number of hydrogen-bonding interactions would enhance the hydrogen-bonding stabilization enthalpy, this stabilization enthalpy per unit would be partially sacrificed to compensate for the entropy loss due to dimerization. These results clearly support the importance of preorganization in designing hydrogen-bonding guest - host molecules.

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Self-complementarity of oligo-2-aminopyridines: A new class of hydrogen-bonded ladders

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 149603: Experimental Crystal Structure Determination

CCDC 149601: Experimental Crystal Structure Determination

CCDC 149602: Experimental Crystal Structure Determination

引用此