Self-adaptation of manganese-chloride arrangement toward high spin Mn 5(μ-Cl) 4 cluster-based metal-organic framework with S = 15/ 2

Shao Hsuan Lin; Chen I. Yang; Ting Shen Kuo; Ming Hsi Chiang; Kung Chung Hsu; Kuang Lieh Lu

doi:10.1039/c2dt11760f

Self-adaptation of manganese-chloride arrangement toward high spin Mn ₅(μ-Cl) ₄ cluster-based metal-organic framework with S = ¹⁵/ ₂

Shao Hsuan Lin, Chen I. Yang, Ting Shen Kuo, Ming Hsi Chiang, Kung Chung Hsu, Kuang Lieh Lu

化學系

研究成果: 雜誌貢獻 › 文章

8 引文斯高帕斯（Scopus）

摘要

The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me ₃-TBzIm) afforded a rare 3D metal-organic framework, [Mn ₅Cl ₁₀(Me ₃-TBzIm) ₄] _n (1) showing a high spin ground state with S = ¹⁵/ ₂.

原文	英語
頁（從 - 到）	1448-1450
頁數	3
期刊	Dalton Transactions
卷	41
發行號	5
DOIs	https://doi.org/10.1039/c2dt11760f
出版狀態	已發佈 - 2012 二月 7

指紋

ASJC Scopus subject areas

Inorganic Chemistry

引用此

Lin, S. H., Yang, C. I., Kuo, T. S., Chiang, M. H., Hsu, K. C., & Lu, K. L. (2012). Self-adaptation of manganese-chloride arrangement toward high spin Mn ₅(μ-Cl) ₄ cluster-based metal-organic framework with S = ¹⁵/ ₂ Dalton Transactions, 41(5), 1448-1450. https://doi.org/10.1039/c2dt11760f

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存取文件

10.1039/c2dt11760f