Selective insertion of oxygen and selenium into an electron-precise aramagnetic selenium-manganese carbonyl cluster [Se6Mn 6(CO)18]4-

Minghuey Shieh*, Chia Hua Ho, Wen Shyan Sheu, Horng Wen Chen

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

15 引文 斯高帕斯(Scopus)

摘要

(Figure Presented) The facile synthesis of a novel electron-precise paramagnetic hexamanganese carbonyl selenide cluster [Se6Mn 6(CO)18]4- (1 ) was discovered, which demonstrates contrasting reactivity toward O2 and Se8 under markedly mild conditions to afford the O- and Se-inserted clusters [Se6Mn6(CO)18(O)]4- (2) and [Se 10Mn6(CO)18]4- (3), respectively. Clusters 1-3 represent the first examples of electron-precise paramagnetic main-group transition metal carbonyl clusters, and their formation and bonding properties are further elucidated by theoretical calculations.

原文英語
頁(從 - 到)4032-4033
頁數2
期刊Journal of the American Chemical Society
132
發行號12
DOIs
出版狀態已發佈 - 2010 3月 31

ASJC Scopus subject areas

  • 催化
  • 一般化學
  • 生物化學
  • 膠體和表面化學

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