Room-temperature phosphorescence from small organic systems containing a thiocarbonyl moiety

Chun Hao Huang; Pei Jhen Wu; Kun You Chung; Yi An Chen; Elise Y. Li; Pi Tai Chou

doi:10.1039/c7cp00074j

Room-temperature phosphorescence from small organic systems containing a thiocarbonyl moiety

Chun Hao Huang, Pei Jhen Wu, Kun You Chung, Yi An Chen, Elise Y. Li^*, Pi Tai Chou

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

18 引文斯高帕斯（Scopus）

摘要

Small organic molecules based on the unnatural DNA base pair dTPT3 are designed and synthesized, among which compounds bearing the thiocarbonyl group, compared with their carbonyl counterparts, show a much larger SOC integral between S₁(¹nπ∗) and T₁(³ππ∗) states due to the appropriate energy level alignment and the heavy sulfur atom effect, resulting in the appearance of both fluorescence and phosphorescence in solution and solid state at room temperature.

原文	英語
頁（從 - 到）	8896-8901
頁數	6
期刊	Physical Chemistry Chemical Physics
卷	19
發行號	13
DOIs	https://doi.org/10.1039/c7cp00074j
出版狀態	已發佈 - 2017

ASJC Scopus subject areas

一般物理與天文學
物理與理論化學

存取文件

10.1039/c7cp00074j

其它文件與鏈接

CCDC 1504812: Experimental Crystal Structure Determination
Huang, C. (Creator), Wu, P. (Creator), Chung, K. (Creator), Chen, Y. (Creator), Li, Y. E. (Creator) & Chou, P. (Creator), Unknown Publisher, 2017
DOI: 10.5517/ccdc.csd.cc1mhwbb, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1mhwbb&sid=DataCite
資料集: Dataset
CCDC 1504811: Experimental Crystal Structure Determination
Huang, C. (Creator), Wu, P. (Creator), Chung, K. (Creator), Chen, Y. (Creator), Li, Y. E. (Creator) & Chou, P. (Creator), Unknown Publisher, 2017
DOI: 10.5517/ccdc.csd.cc1mhw99, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1mhw99&sid=DataCite
資料集: Dataset
CCDC 1504810: Experimental Crystal Structure Determination
Huang, C. (Creator), Wu, P. (Creator), Chung, K. (Creator), Chen, Y. (Creator), Li, Y. E. (Creator) & Chou, P. (Creator), Unknown Publisher, 2017
DOI: 10.5517/ccdc.csd.cc1mhw88, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1mhw88&sid=DataCite
資料集: Dataset

引用此

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abstract = "Small organic molecules based on the unnatural DNA base pair dTPT3 are designed and synthesized, among which compounds bearing the thiocarbonyl group, compared with their carbonyl counterparts, show a much larger SOC integral between S1(1nπ∗) and T1(3ππ∗) states due to the appropriate energy level alignment and the heavy sulfur atom effect, resulting in the appearance of both fluorescence and phosphorescence in solution and solid state at room temperature.",

author = "Huang, {Chun Hao} and Wu, {Pei Jhen} and Chung, {Kun You} and Chen, {Yi An} and Li, {Elise Y.} and Chou, {Pi Tai}",

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year = "2017",

doi = "10.1039/c7cp00074j",

language = "English",

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pages = "8896--8901",

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AU - Huang, Chun Hao

AU - Wu, Pei Jhen

AU - Chung, Kun You

AU - Chen, Yi An

AU - Li, Elise Y.

AU - Chou, Pi Tai

PY - 2017

Y1 - 2017

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AB - Small organic molecules based on the unnatural DNA base pair dTPT3 are designed and synthesized, among which compounds bearing the thiocarbonyl group, compared with their carbonyl counterparts, show a much larger SOC integral between S1(1nπ∗) and T1(3ππ∗) states due to the appropriate energy level alignment and the heavy sulfur atom effect, resulting in the appearance of both fluorescence and phosphorescence in solution and solid state at room temperature.

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JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 13

ER -

Room-temperature phosphorescence from small organic systems containing a thiocarbonyl moiety

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 1504812: Experimental Crystal Structure Determination

CCDC 1504811: Experimental Crystal Structure Determination

CCDC 1504810: Experimental Crystal Structure Determination

引用此