Room-temperature phosphorescence from small organic systems containing a thiocarbonyl moiety

Chun Hao Huang, Pei Jhen Wu, Kun You Chung, Yi An Chen, Elise Y. Li, Pi Tai Chou

研究成果: 雜誌貢獻文章同行評審

8 引文 斯高帕斯(Scopus)

摘要

Small organic molecules based on the unnatural DNA base pair dTPT3 are designed and synthesized, among which compounds bearing the thiocarbonyl group, compared with their carbonyl counterparts, show a much larger SOC integral between S1(1nπ∗) and T1(3ππ∗) states due to the appropriate energy level alignment and the heavy sulfur atom effect, resulting in the appearance of both fluorescence and phosphorescence in solution and solid state at room temperature.

原文英語
頁(從 - 到)8896-8901
頁數6
期刊Physical Chemistry Chemical Physics
19
發行號13
DOIs
出版狀態已發佈 - 2017

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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