Ring Opening of a meso-Triaryl 25-Oxasmaragdyrin Macrocycle by m-Chloroperoxybenzoic Acid

Hemanta Kalita; Avijit Ghosh; Way Zen Lee; Mangalampalli Ravikanth

doi:10.1002/chem.201503905

Ring Opening of a meso-Triaryl 25-Oxasmaragdyrin Macrocycle by m-Chloroperoxybenzoic Acid

Hemanta Kalita, Avijit Ghosh, Way Zen Lee, Mangalampalli Ravikanth^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

2 引文斯高帕斯（Scopus）

摘要

Smaragdyrin, a class of expanded porphyrin macrocycles, upon treatment with meta-chloroperoxybenzoic acid (mCPBA) underwent oxidative ring opening to form an unprecedented linear pentaheterocyclic compound. The linear pentaheterocyclic compound was freely soluble in common organic solvents and characterized in detail by HRMS, 1D and 2D NMR spectroscopy, and X-ray crystallography. Our preliminary studies indicated that the linear pentaheterocyclic compound can specifically sense anions such as H₂PO₄ ^- and CN^- ions, which was corroborated by absorption and fluorescence studies.

原文	英語
頁（從 - 到）	2153-2157
頁數	5
期刊	Chemistry - A European Journal
卷	22
發行號	6
DOIs	https://doi.org/10.1002/chem.201503905
出版狀態	已發佈 - 2016 2月 5

ASJC Scopus subject areas

一般化學
催化
有機化學

存取文件

10.1002/chem.201503905

其它文件與鏈接

CCDC 1420187: Experimental Crystal Structure Determination
Kalita, H. (Creator), Ghosh, A. (Creator), Lee, W. (Creator) & Ravikanth, M. (Creator), Unknown Publisher, 2016
DOI: 10.5517/cc1jnthh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1jnthh&sid=DataCite
資料集: Dataset

引用此

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title = "Ring Opening of a meso-Triaryl 25-Oxasmaragdyrin Macrocycle by m-Chloroperoxybenzoic Acid",

abstract = "Smaragdyrin, a class of expanded porphyrin macrocycles, upon treatment with meta-chloroperoxybenzoic acid (mCPBA) underwent oxidative ring opening to form an unprecedented linear pentaheterocyclic compound. The linear pentaheterocyclic compound was freely soluble in common organic solvents and characterized in detail by HRMS, 1D and 2D NMR spectroscopy, and X-ray crystallography. Our preliminary studies indicated that the linear pentaheterocyclic compound can specifically sense anions such as H2PO4 - and CN- ions, which was corroborated by absorption and fluorescence studies.",

keywords = "anion sensing, isosbestic point, meta-chloroperoxybenzoic acid, ring-opening reactions, smaragdyrin",

author = "Hemanta Kalita and Avijit Ghosh and Lee, {Way Zen} and Mangalampalli Ravikanth",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

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T1 - Ring Opening of a meso-Triaryl 25-Oxasmaragdyrin Macrocycle by m-Chloroperoxybenzoic Acid

AU - Kalita, Hemanta

AU - Ghosh, Avijit

AU - Lee, Way Zen

AU - Ravikanth, Mangalampalli

PY - 2016/2/5

Y1 - 2016/2/5

N2 - Smaragdyrin, a class of expanded porphyrin macrocycles, upon treatment with meta-chloroperoxybenzoic acid (mCPBA) underwent oxidative ring opening to form an unprecedented linear pentaheterocyclic compound. The linear pentaheterocyclic compound was freely soluble in common organic solvents and characterized in detail by HRMS, 1D and 2D NMR spectroscopy, and X-ray crystallography. Our preliminary studies indicated that the linear pentaheterocyclic compound can specifically sense anions such as H2PO4 - and CN- ions, which was corroborated by absorption and fluorescence studies.

AB - Smaragdyrin, a class of expanded porphyrin macrocycles, upon treatment with meta-chloroperoxybenzoic acid (mCPBA) underwent oxidative ring opening to form an unprecedented linear pentaheterocyclic compound. The linear pentaheterocyclic compound was freely soluble in common organic solvents and characterized in detail by HRMS, 1D and 2D NMR spectroscopy, and X-ray crystallography. Our preliminary studies indicated that the linear pentaheterocyclic compound can specifically sense anions such as H2PO4 - and CN- ions, which was corroborated by absorption and fluorescence studies.

KW - anion sensing

KW - isosbestic point

KW - meta-chloroperoxybenzoic acid

KW - ring-opening reactions

KW - smaragdyrin

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

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ER -

Ring Opening of a meso-Triaryl 25-Oxasmaragdyrin Macrocycle by m-Chloroperoxybenzoic Acid

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 1420187: Experimental Crystal Structure Determination

引用此