Ring Opening of a meso-Triaryl 25-Oxasmaragdyrin Macrocycle by m-Chloroperoxybenzoic Acid

Hemanta Kalita, Avijit Ghosh, Way Zen Lee, Mangalampalli Ravikanth

研究成果: 雜誌貢獻文章

2 引文 斯高帕斯(Scopus)

摘要

Smaragdyrin, a class of expanded porphyrin macrocycles, upon treatment with meta-chloroperoxybenzoic acid (mCPBA) underwent oxidative ring opening to form an unprecedented linear pentaheterocyclic compound. The linear pentaheterocyclic compound was freely soluble in common organic solvents and characterized in detail by HRMS, 1D and 2D NMR spectroscopy, and X-ray crystallography. Our preliminary studies indicated that the linear pentaheterocyclic compound can specifically sense anions such as H2PO4 - and CN- ions, which was corroborated by absorption and fluorescence studies.

原文英語
頁(從 - 到)2153-2157
頁數5
期刊Chemistry - A European Journal
22
發行號6
DOIs
出版狀態已發佈 - 2016 二月 5

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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