Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction: Facile approach to tricarbocycles

Ming Chang P. Yeh; Wen Cheng Tsao; Jin Shen Ho; Chih Chuan Tai; Dai Yu Chiou; Ling Hsien Tu

doi:10.1021/om030634p

Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction: Facile approach to tricarbocycles

Ming Chang P. Yeh^*, Wen Cheng Tsao, Jin Shen Ho, Chih Chuan Tai, Dai Yu Chiou, Ling Hsien Tu

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

19 引文斯高帕斯（Scopus）

摘要

The rhodium-catalyzed Pauson - Khand reaction (PKR) of cyclohexa-l,3-dienes containing two methylene carbons and an alkyne in a chain produced regular PKR products. Cyclohexadienynes bearing three methylene units and a aromatic ring at the alkyne afforded regular PKR products and angularly fused tricyclic compounds, which were derived from diene migration followed by the PKR process.

原文	英語
頁（從 - 到）	792-799
頁數	8
期刊	Organometallics
卷	23
發行號	4
DOIs	https://doi.org/10.1021/om030634p
出版狀態	已發佈 - 2004 2月 16

ASJC Scopus subject areas

物理與理論化學
有機化學
無機化學

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10.1021/om030634p

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abstract = "The rhodium-catalyzed Pauson - Khand reaction (PKR) of cyclohexa-l,3-dienes containing two methylene carbons and an alkyne in a chain produced regular PKR products. Cyclohexadienynes bearing three methylene units and a aromatic ring at the alkyne afforded regular PKR products and angularly fused tricyclic compounds, which were derived from diene migration followed by the PKR process.",

author = "Yeh, \{Ming Chang P.\} and Tsao, \{Wen Cheng\} and Ho, \{Jin Shen\} and Tai, \{Chih Chuan\} and Chiou, \{Dai Yu\} and Tu, \{Ling Hsien\}",

year = "2004",

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day = "16",

doi = "10.1021/om030634p",

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T2 - Facile approach to tricarbocycles

AU - Yeh, Ming Chang P.

AU - Tsao, Wen Cheng

AU - Ho, Jin Shen

AU - Tai, Chih Chuan

AU - Chiou, Dai Yu

AU - Tu, Ling Hsien

PY - 2004/2/16

Y1 - 2004/2/16

N2 - The rhodium-catalyzed Pauson - Khand reaction (PKR) of cyclohexa-l,3-dienes containing two methylene carbons and an alkyne in a chain produced regular PKR products. Cyclohexadienynes bearing three methylene units and a aromatic ring at the alkyne afforded regular PKR products and angularly fused tricyclic compounds, which were derived from diene migration followed by the PKR process.

AB - The rhodium-catalyzed Pauson - Khand reaction (PKR) of cyclohexa-l,3-dienes containing two methylene carbons and an alkyne in a chain produced regular PKR products. Cyclohexadienynes bearing three methylene units and a aromatic ring at the alkyne afforded regular PKR products and angularly fused tricyclic compounds, which were derived from diene migration followed by the PKR process.

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JO - Organometallics

JF - Organometallics

IS - 4

ER -

Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction: Facile approach to tricarbocycles

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