Remarkable reaction rate and excellent enantioselective direct α-amination of aldehydes with azodicarboxylates catalyzed by pyrrolidinylcamphor-derived organocatalysts

Pang Min Liu, Chihliang Chang, Raju Jannapu Reddy, Ying Fang Ting, Hsuan Hao Kuan, Kwunmin Chen*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

38 引文 斯高帕斯(Scopus)

摘要

Remarkable reaction rate and excellent enantioselective direct α-amination of unmodified aldehydes with various azodicarboxylates was catalyzed by pyrrolidinylcamphor organocatalyst 2a (5 mol-%) to provide the desired aminated products with excellent chemical yields and high to excellent levels of enantioselectivity (up to >99%ee) at 0 °C in CH 2Cl2.

原文英語
頁(從 - 到)42-46
頁數5
期刊European Journal of Organic Chemistry
發行號1
DOIs
出版狀態已發佈 - 2010

ASJC Scopus subject areas

  • 物理與理論化學
  • 有機化學

指紋

深入研究「Remarkable reaction rate and excellent enantioselective direct α-amination of aldehydes with azodicarboxylates catalyzed by pyrrolidinylcamphor-derived organocatalysts」主題。共同形成了獨特的指紋。

引用此