Reactivities of the chalcogen-capped triiron clusters [EFe3 (CO)9]2- (E = Te, Se, S): Cluster growth and transformations

Minghuey Shieh*, Chia Hua Ho

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

8 引文 斯高帕斯(Scopus)

摘要

Transition-metal carbonyl clusters incorporated with chalcogen elements are of particular interests due to their structural and chemical diversity. Up to now, quite a large number of chalcogen-containing iron carbonyl clusters have been synthesized and structurally characterized. In this short review, we will describe our recent developments on the interesting cluster expansions and transformations of the chalcogen-capped triiron clusters [EFe3(CO)9] 2- (E = Te, 1; Se, 2; S, 3) toward a series of organic and inorganic electrophiles. The effects of chalcogen atoms and the incoming electrophiles on the formation of the resultant clusters are also compared and discussed.

原文英語
頁(從 - 到)1838-1849
頁數12
期刊Comptes Rendus Chimie
8
發行號11-12
DOIs
出版狀態已發佈 - 2005

ASJC Scopus subject areas

  • 化學 (全部)
  • 化學工程 (全部)

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