Reactions of (η3-allyl)tetracarbonyliron cations with the highly functionalized copper reagents RCu(CN)Znl

Ming Chang P. Yeh; Sheng I. Tau

doi:10.1039/C39920000013

Reactions of (η³-allyl)tetracarbonyliron cations with the highly functionalized copper reagents RCu(CN)Znl

Ming Chang P. Yeh^*, Sheng I. Tau

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

25 引文斯高帕斯（Scopus）

摘要

The addition of the highly functionalized copper reagents RCu(CN)Znl to (η³-allyl)Fe(CO)₄ cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.

原文	英語
頁（從 - 到）	13-15
頁數	3
期刊	Journal of the Chemical Society, Chemical Communications
發行號	1
DOIs	https://doi.org/10.1039/C39920000013
出版狀態	已發佈 - 1992

ASJC Scopus subject areas

分子醫學

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10.1039/C39920000013

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引用此

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title = "Reactions of (η3-allyl)tetracarbonyliron cations with the highly functionalized copper reagents RCu(CN)Znl",

abstract = "The addition of the highly functionalized copper reagents RCu(CN)Znl to (η3-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.",

author = "Yeh, {Ming Chang P.} and Tau, {Sheng I.}",

year = "1992",

doi = "10.1039/C39920000013",

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AU - Yeh, Ming Chang P.

AU - Tau, Sheng I.

PY - 1992

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N2 - The addition of the highly functionalized copper reagents RCu(CN)Znl to (η3-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.

AB - The addition of the highly functionalized copper reagents RCu(CN)Znl to (η3-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.

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Reactions of (η3-allyl)tetracarbonyliron cations with the highly functionalized copper reagents RCu(CN)Znl

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

引用此

Reactions of (η³-allyl)tetracarbonyliron cations with the highly functionalized copper reagents RCu(CN)Znl