Reactions of (η3-allyl)tetracarbonyliron cations with the highly functionalized copper reagents RCu(CN)Znl

Ming Chang P. Yeh*, Sheng I. Tau

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

25 引文 斯高帕斯(Scopus)

摘要

The addition of the highly functionalized copper reagents RCu(CN)Znl to (η3-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.

原文英語
頁(從 - 到)13-15
頁數3
期刊Journal of the Chemical Society, Chemical Communications
發行號1
DOIs
出版狀態已發佈 - 1992

ASJC Scopus subject areas

  • 分子醫學

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