Reactions of β‐nitrostyrenes with tert‐butylmercury halides in the presence of lodide lon

Glen A. Russell*, Ching‐Fa ‐F Yao

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

12 引文 斯高帕斯(Scopus)

摘要

Photolysis of t‐BuHgCl/KI with PhC(R2)C(R1)NO2 forms PhC(R2)C(R1)Bu‐t when R1 = R2 = H or in low yield when R1 = H, R2 = Ph. When R1 ≠ H, or when R2 = Ph, reactions with t‐BuHgI/KI/hv proceed mainly via PhC(R2)C(R1)NO2·‐, PhC(R2)C(R1)N(OBu‐t)OHgX+, PhC(R2)C(R1)NO and PhC(R2)C(R1)N(OBu‐t)HgX to form a variety of novel products including the dimeric bisnitronic esters (6) with R1 = Me or Ph and R2 = H; PhCH(R2)C(R1) = NOBu‐t with R1 = Me or Ph and R2 = H or R1 = H and R2 = Ph; PhC(R2)(OBu‐t)C(R1)NOH with R1 = H or Me and R2 = Ph; and 3‐phenyl‐2‐R1‐indoles with R1 = H, Me, Ph, PhS or t‐BuS and R2 = Ph. Nitrosoaromatics react with t‐BuHgX in the dark to form ArN(OBu‐t)(OBu‐t)HgX+ which condenses with ArNO to form the azoxy compound. tert‐Butyl radicals will add to RNO2 [R = Ph, Ph2CCH, Ph2CC(Ph)] in the presence of t‐BuHgI2 to form products derived from RN(OBu‐t)OHgI+.

原文英語
頁(從 - 到)209-218
頁數10
期刊Heteroatom Chemistry
3
發行號3
DOIs
出版狀態已發佈 - 1992 六月
對外發佈

ASJC Scopus subject areas

  • 化學 (全部)

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