Reactions of β-nitrostyrenes with Grignard reagents

Ching Fa Yao; Wen Chang Chen; Yu Mei Lin

doi:10.1016/0040-4039(96)01366-4

Reactions of β-nitrostyrenes with Grignard reagents

Ching Fa Yao^*
, Wen Chang Chen
, Yu Mei Lin

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

30 引文斯高帕斯（Scopus）

摘要

α-Phenyl-β-nitrostyrene 1a and β-nitrostyrene 1b react with Grignard reagents to generate hydroxyimoyl halides 3 or nitrile oxides 4 after workup with ice cold concentrated aqueous HX acid solution. Carboxylic acids 5 are the only products isolated from 1b and products 3 or 4 are still obtained from 1a when concentrated sulfuric acid solution is used.

原文	英語
頁（從 - 到）	6339-6342
頁數	4
期刊	Tetrahedron Letters
卷	37
發行號	35
DOIs	https://doi.org/10.1016/0040-4039(96)01366-4
出版狀態	已發佈 - 1996 8月 26

ASJC Scopus subject areas

生物化學
藥物發現
有機化學

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10.1016/0040-4039(96)01366-4

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title = "Reactions of β-nitrostyrenes with Grignard reagents",

abstract = "α-Phenyl-β-nitrostyrene 1a and β-nitrostyrene 1b react with Grignard reagents to generate hydroxyimoyl halides 3 or nitrile oxides 4 after workup with ice cold concentrated aqueous HX acid solution. Carboxylic acids 5 are the only products isolated from 1b and products 3 or 4 are still obtained from 1a when concentrated sulfuric acid solution is used.",

author = "Yao, \{Ching Fa\} and Chen, \{Wen Chang\} and Lin, \{Yu Mei\}",

note = "Funding Information: Acknowledgment. The financial support by the National Science Council of R.O.C. (Grant NSC 83-0208-M-003-032) and X-ray data are collected and processed by professor C.-H. Ueng of National Taiwan Normal University are gratefully acknowledged.",

year = "1996",

month = aug,

day = "26",

doi = "10.1016/0040-4039(96)01366-4",

language = "English",

volume = "37",

pages = "6339--6342",

journal = "Tetrahedron Letters",

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T1 - Reactions of β-nitrostyrenes with Grignard reagents

AU - Yao, Ching Fa

AU - Chen, Wen Chang

AU - Lin, Yu Mei

N1 - Funding Information: Acknowledgment. The financial support by the National Science Council of R.O.C. (Grant NSC 83-0208-M-003-032) and X-ray data are collected and processed by professor C.-H. Ueng of National Taiwan Normal University are gratefully acknowledged.

PY - 1996/8/26

Y1 - 1996/8/26

N2 - α-Phenyl-β-nitrostyrene 1a and β-nitrostyrene 1b react with Grignard reagents to generate hydroxyimoyl halides 3 or nitrile oxides 4 after workup with ice cold concentrated aqueous HX acid solution. Carboxylic acids 5 are the only products isolated from 1b and products 3 or 4 are still obtained from 1a when concentrated sulfuric acid solution is used.

AB - α-Phenyl-β-nitrostyrene 1a and β-nitrostyrene 1b react with Grignard reagents to generate hydroxyimoyl halides 3 or nitrile oxides 4 after workup with ice cold concentrated aqueous HX acid solution. Carboxylic acids 5 are the only products isolated from 1b and products 3 or 4 are still obtained from 1a when concentrated sulfuric acid solution is used.

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UR - https://www.scopus.com/pages/publications/0030603037#tab=citedBy

U2 - 10.1016/0040-4039(96)01366-4

DO - 10.1016/0040-4039(96)01366-4

M3 - Article

AN - SCOPUS:0030603037

SN - 0040-4039

VL - 37

SP - 6339

EP - 6342

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 35

ER -

Reactions of β-nitrostyrenes with Grignard reagents

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