Reactions of β-nitrostyrenes with Grignard reagents

Ching Fa Yao*, Wen Chang Chen, Yu Mei Lin

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

29 引文 斯高帕斯(Scopus)

摘要

α-Phenyl-β-nitrostyrene 1a and β-nitrostyrene 1b react with Grignard reagents to generate hydroxyimoyl halides 3 or nitrile oxides 4 after workup with ice cold concentrated aqueous HX acid solution. Carboxylic acids 5 are the only products isolated from 1b and products 3 or 4 are still obtained from 1a when concentrated sulfuric acid solution is used.

原文英語
頁(從 - 到)6339-6342
頁數4
期刊Tetrahedron Letters
37
發行號35
DOIs
出版狀態已發佈 - 1996 8月 26

ASJC Scopus subject areas

  • 生物化學
  • 藥物發現
  • 有機化學

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