TY - JOUR
T1 - Reaction of Tricarbonyl(η3‐allyl)iron(0) Anions with Bromine
AU - Yeh, Ming‐Chang P.
AU - Kang, Kuo‐Ping ‐P
AU - Hwu, Chong‐Chen ‐C
PY - 1991/10
Y1 - 1991/10
N2 - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at 23°C to give putative tricarbonyl(η3‐allyl)iron(0) anion complexes. Trapping of the reactive intermediates with bromine produced nucleophilic‐substituted tricarbonyl(η4‐1,3‐diene)iron(0) complexes.
AB - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at 23°C to give putative tricarbonyl(η3‐allyl)iron(0) anion complexes. Trapping of the reactive intermediates with bromine produced nucleophilic‐substituted tricarbonyl(η4‐1,3‐diene)iron(0) complexes.
KW - (η‐Allyl) syn/anti isomerization
KW - Reductive elimination
KW - Tricarbonyl(η‐allyl)iron(0) anionic complexes
KW - β‐Hydride elimination
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U2 - 10.1002/jccs.199100079
DO - 10.1002/jccs.199100079
M3 - Article
AN - SCOPUS:84985095008
VL - 38
SP - 475
EP - 482
JO - Journal of the Chinese Chemical Society
JF - Journal of the Chinese Chemical Society
SN - 0009-4536
IS - 5
ER -